This thesis deals with ancient Greek nominal compounds with a prepositional first member (FM), and in particular the case of the FM \u1f10\u3bd\ub0. I analyse a great amount of words from a morphological and semantical point of view. The pool of words is based on a formal criterion; the goal of the analysis is to outline different processes of compound formation, as well as their evolution. As compared to other compounds, those with a prepositional FM present two special characteristics: first, they are not formed by two lexemes, since prepositions/adverbs are not real lexemes; secondly, their internal structure is not often recognizable. The guide-questions of this research are: does the special nature of prepositional FM compounds change ...