This review covers the innovative and promising area of syntheses of metal carbonyl complexes and clusters mediated by the surface of inorganic oxides. Emphasis is placed on syntheses which allow comparison of yields and reaction conditions with respect to traditional syntheses in solution. The use of the silica surface is described first, followed by MgO, Al2O3, ZnO, and La2O3. Furthermore, brief mention is made of the synthesis of metal carbonyl clusters in the cages of zeolites. Finally, the role of the syntheses mediated by the surface of inorganic oxides as a spring of inspiration for syntheses of metal carbonyl clusters in solution is outlined
Various guests have been investigated in zeolite hosts in our laboratory over the past five years. F...
Many metal–organic frameworks (MOFs) incorporate nodes that are small metal oxide clusters. Some of ...
Zeolite encapsulated transition metal complexes have received wide attention as an effective heterog...
Catalytic oxidation is a key technology for the conversion of petroleum-based feedstocks into useful...
Abstract.- The study of the reactions of organometallic complexes with the surfaces of inorganic oxi...
[Os3(CO)12], [H4Os4(CO)12], [H2Os4(CO)12]2-, [Os5C(CO)14]2-, and [Os10C(CO)24]2- have been synthesiz...
Activation of [Os3(CO)12] by the silica surface via reaction with surface silanol groups provides a ...
Reaction of silica-supported \u3b1-[Os(CO)3Cl2]2 in the presence of alkali-metal carbonates affords ...
ABSTRACT: The synthesis protocols for encapsulation of metal clusters reported here expand the diver...
Synthesis o f clusters o f acicular MFI zeolites from porous silica layers strongly attached to stai...
The study of the reactions of organometallic complexes with the surfaces of inorganic oxides, zeolit...
Chemical methods of synthesis of materials play a crucial role in designing and discovering new mate...
A review; in this chapter, the emphasis moves to reactivity at metal ion sites in zeolites. One of t...
The selective encapsulation of metal clusters within zeolites can be used to prepare clusters that a...
The synthesis protocols for encapsulation of metal clusters reported here expand the diversity in ca...
Various guests have been investigated in zeolite hosts in our laboratory over the past five years. F...
Many metal–organic frameworks (MOFs) incorporate nodes that are small metal oxide clusters. Some of ...
Zeolite encapsulated transition metal complexes have received wide attention as an effective heterog...
Catalytic oxidation is a key technology for the conversion of petroleum-based feedstocks into useful...
Abstract.- The study of the reactions of organometallic complexes with the surfaces of inorganic oxi...
[Os3(CO)12], [H4Os4(CO)12], [H2Os4(CO)12]2-, [Os5C(CO)14]2-, and [Os10C(CO)24]2- have been synthesiz...
Activation of [Os3(CO)12] by the silica surface via reaction with surface silanol groups provides a ...
Reaction of silica-supported \u3b1-[Os(CO)3Cl2]2 in the presence of alkali-metal carbonates affords ...
ABSTRACT: The synthesis protocols for encapsulation of metal clusters reported here expand the diver...
Synthesis o f clusters o f acicular MFI zeolites from porous silica layers strongly attached to stai...
The study of the reactions of organometallic complexes with the surfaces of inorganic oxides, zeolit...
Chemical methods of synthesis of materials play a crucial role in designing and discovering new mate...
A review; in this chapter, the emphasis moves to reactivity at metal ion sites in zeolites. One of t...
The selective encapsulation of metal clusters within zeolites can be used to prepare clusters that a...
The synthesis protocols for encapsulation of metal clusters reported here expand the diversity in ca...
Various guests have been investigated in zeolite hosts in our laboratory over the past five years. F...
Many metal–organic frameworks (MOFs) incorporate nodes that are small metal oxide clusters. Some of ...
Zeolite encapsulated transition metal complexes have received wide attention as an effective heterog...