A novel high-nuclearity rhodium carbonyl cluster compound containing two interstitial nitrogen atoms : Synthesis and X-ray structure of the anion [Rh 14N2(CO)25]2

Hexagonal close packing of metal atoms in the new polynuclear anions [Rh13(CO)24H5-n]n- (n=2 or 3); x-ray structure of [(Ph3P)2N]2[Rh13(CO)24H3].

V.G.Albano
A.Ceriotti
P.Chini
G.Ciani
S.Martinengo
W.M.Anker

January 1975

The [Rh13(CO)24H5-n]n- (n = 2 or 3) anions have been isolated from the reaction of the [Rh12(CO) 30]...

SYNTHESIS OF 2 NOVEL PENTANUCLEAR RHODIUM CLUSTERS BEARING THE ALKYL-LIKE LIGANDS CH2COOME AND CH2CN - X-RAY STRUCTURE OF [PPH4]2[RH5(MU-CO)6(CO)8(CH2CN)]

F. RAGAINI
F. PORTA
A. FUMAGALLI
F. DEMARTIN

January 1991

The reaction of [PPh4][Rh(CO)4] (1) under CO with BrCH2COOMe or BrCH2CN in a 5:3 molar ratio gave hi...

Synthesis, X-ray crystal structure and 13C NMR study of the anion [Re6(\u3bc3-H)2C(CO)18]2-: The first octahedral carbonyl cluster of rhenium

G. Ciani
G. D'Alfonso
P. Romiti
A. Sironi
M. Freni

January 1983

The novel high nuclearity carbido-carbonyl anion [Re6(\u3bc3-H)2C(CO)18]2-, isolated from the pyroly...

A large rhodium carbonyl cluster compound containing four encapsulated nitrogen atoms: Synthesis and X-ray structure of the anion [Rh 23N4(CO)20(\u3bc-CO)18]3

S. Martinengo
G. Ciani
A. Sironi

January 1992

The novel anion [Rh23N4(CO)20(\u3bc-CO) 18]3-, obtained by controlled pyrolysis of [Rh 6N(CO)15]-, c...

A novel hydridic high-nuclearity rhodium cluster: synthesis and x-ray crystal structure of the anion [Rh14H(\u3bc-CO)15(CO)10]3

G. Ciani
A. Sironi
S. Martinengo

January 1980

The novel anion [Rh14H(CO)25]3- has been obtained by reaction of the tetra-anion [Rh14(CO)25]4- with...

Synthesis and x-ray crystal structure of the novel high nuclearity rhodium-cluster dianion [Rh14(\u3bc-CO)15(CO) 11]2

S. Martinengo
G. Ciani
A. Sironi

January 1980

An X-ray crystallographic study has shown that the novel dianion [Rh 14(CO)26]2-, which has been iso...

Synthesis and x-ray crystal structure of the novel cluster anion [Rh 12H(N)2(CO)23]3-; an irregular metallic array containing two interstitial nitrogen atoms

S. Martinengo
G. Ciani
A. Sironi

January 1986

The anion [Rh12H(N)2(CO)23]3-, obtained by alkaline pyrolysis of [Rh6N(CO)15] -, contains a novel ir...

High nuclearity carbido carbonyl clusters of rhenium. Synthesis, x-ray crystal structure, and 13C N.M.R. study of the anion [Re 8C(CO)24]2

G. Ciani
G. D'Alfonso
M. Freni
P. Romiti
A. Sironi

January 1982

The novel high nuclearity carbido carbonyl anion [Re8C(CO) 24]2-, isolated from the pyrolysis of [Re...

High nuclearity carbonyl clusters of rhodium. Synthesis and crystal structure of (NMe4)3[Rh14H(CO)25] \ub7 Me2CO

G. Ciani
M. Moret
A. Sironi
S. Martinengo

January 1989

The compound (NMe4)3[Rh14H(CO)25] \ub7 Me2CO has been obtained by treatment of (NMe4)4[Rh14(CO)25] w...

Synthesis and x-ray characterization of the high-nuclearity [Rh 17(\u3bc3-CO)3-(\u3bc-CO)15(CO) 12]3- anion containing a tetracapped twinned cuboctahedral cluster

G. Ciani
A. Magni
A. Sironi
S. Martinengo

January 1981

The novel anion [Rh17(CO)30]3-, which has been obtained by refluxing a mixture of Rh4(CO)12 and NaOH...

New High-Nuclearity Carbonyl and Carbonyl-Substituted Rhodium Clusters and Their Relationships with Polyicosahedral Carbonyl-Substituted Palladium and Gold-Thiolates

July 2015

none6noA reinvestigation of the synthesis of [H5−nRh13(CO)24]n− (n = 2, 3) led to isolat...

Synthesis and structural characterization of the anion [Rh6(CO)14(\u3b73-C3H5)]

G. Ciani
A. Sironi
P. Chini
A. Ceriotti
S. Martinengo

January 1980

The anion [Rh6(CO)14(CP3H5]-, obtained by reaction of [Rh6(CO)15]2- with allyl chloride, contains an...

A high nuclearity carbonyl cluster of rhenium stabilized by an interstitial carbide; synthesis and x-ray crystal structure of the anion [Re7C(CO)21]3

G. Ciani
G. D'Alfonso
M. Freni
P. Romiti
A. Sironi

January 1982

The trianion [Re7C(CO)21]3-, isolated from the pyrolysis of [ReH2(CO)4][NEt4] in n-tetradecane, has ...

A new high nuclearity cobalt nitrido-carbonyl cluster. Synthesis and crystal structure of the anion [Co14N3(CO)26]3

S. Martinengo
G. Ciani
A. Sironi

January 1988

The high nuclearity anion [Co14N13(CO)26]3-, obtained by pyrolysis in diglyme of the trigonal prisma...

New High-Nuclearity Carbonyl and Carbonyl-Substituted Rhodium Clusters and Their Relationships with Polyicosahedral Carbonyl-Substituted Palladium- and Gold-Thiolates

Dmitriy S. Dolzhnikov (1510894)
Maria C. Iapalucci (2028250)
Giuliano Longoni (1750657)
Cristina Tiozzo (1404871)
Stefano Zacchini (1431607)
Cristina Femoni (1692355)

November 2012

A reinvestigation of the synthesis of [H5–nRh13(CO)24]<...

Hexagonal close packing of metal atoms in the new polynuclear anions [Rh13(CO)24H5-n]n- (n=2 or 3); x-ray structure of [(Ph3P)2N]2[Rh13(CO)24H3].

V.G.Albano
A.Ceriotti
P.Chini
G.Ciani
S.Martinengo
W.M.Anker

January 1975

The [Rh13(CO)24H5-n]n- (n = 2 or 3) anions have been isolated from the reaction of the [Rh12(CO) 30]...

SYNTHESIS OF 2 NOVEL PENTANUCLEAR RHODIUM CLUSTERS BEARING THE ALKYL-LIKE LIGANDS CH2COOME AND CH2CN - X-RAY STRUCTURE OF [PPH4]2[RH5(MU-CO)6(CO)8(CH2CN)]

F. RAGAINI
F. PORTA
A. FUMAGALLI
F. DEMARTIN

January 1991

The reaction of [PPh4][Rh(CO)4] (1) under CO with BrCH2COOMe or BrCH2CN in a 5:3 molar ratio gave hi...

Synthesis, X-ray crystal structure and 13C NMR study of the anion [Re6(\u3bc3-H)2C(CO)18]2-: The first octahedral carbonyl cluster of rhenium

G. Ciani
G. D'Alfonso
P. Romiti
A. Sironi
M. Freni

January 1983

The novel high nuclearity carbido-carbonyl anion [Re6(\u3bc3-H)2C(CO)18]2-, isolated from the pyroly...

A large rhodium carbonyl cluster compound containing four encapsulated nitrogen atoms: Synthesis and X-ray structure of the anion [Rh 23N4(CO)20(\u3bc-CO)18]3

S. Martinengo
G. Ciani
A. Sironi

January 1992

The novel anion [Rh23N4(CO)20(\u3bc-CO) 18]3-, obtained by controlled pyrolysis of [Rh 6N(CO)15]-, c...

A novel hydridic high-nuclearity rhodium cluster: synthesis and x-ray crystal structure of the anion [Rh14H(\u3bc-CO)15(CO)10]3

G. Ciani
A. Sironi
S. Martinengo

January 1980

The novel anion [Rh14H(CO)25]3- has been obtained by reaction of the tetra-anion [Rh14(CO)25]4- with...

Synthesis and x-ray crystal structure of the novel high nuclearity rhodium-cluster dianion [Rh14(\u3bc-CO)15(CO) 11]2

S. Martinengo
G. Ciani
A. Sironi

January 1980

An X-ray crystallographic study has shown that the novel dianion [Rh 14(CO)26]2-, which has been iso...

Synthesis and x-ray crystal structure of the novel cluster anion [Rh 12H(N)2(CO)23]3-; an irregular metallic array containing two interstitial nitrogen atoms

S. Martinengo
G. Ciani
A. Sironi

January 1986

The anion [Rh12H(N)2(CO)23]3-, obtained by alkaline pyrolysis of [Rh6N(CO)15] -, contains a novel ir...

High nuclearity carbido carbonyl clusters of rhenium. Synthesis, x-ray crystal structure, and 13C N.M.R. study of the anion [Re 8C(CO)24]2

G. Ciani
G. D'Alfonso
M. Freni
P. Romiti
A. Sironi

January 1982

The novel high nuclearity carbido carbonyl anion [Re8C(CO) 24]2-, isolated from the pyrolysis of [Re...

High nuclearity carbonyl clusters of rhodium. Synthesis and crystal structure of (NMe4)3[Rh14H(CO)25] \ub7 Me2CO

G. Ciani
M. Moret
A. Sironi
S. Martinengo

January 1989

The compound (NMe4)3[Rh14H(CO)25] \ub7 Me2CO has been obtained by treatment of (NMe4)4[Rh14(CO)25] w...

Synthesis and x-ray characterization of the high-nuclearity [Rh 17(\u3bc3-CO)3-(\u3bc-CO)15(CO) 12]3- anion containing a tetracapped twinned cuboctahedral cluster

G. Ciani
A. Magni
A. Sironi
S. Martinengo

January 1981

The novel anion [Rh17(CO)30]3-, which has been obtained by refluxing a mixture of Rh4(CO)12 and NaOH...

New High-Nuclearity Carbonyl and Carbonyl-Substituted Rhodium Clusters and Their Relationships with Polyicosahedral Carbonyl-Substituted Palladium and Gold-Thiolates

July 2015

none6noA reinvestigation of the synthesis of [H5−nRh13(CO)24]n− (n = 2, 3) led to isolat...

Synthesis and structural characterization of the anion [Rh6(CO)14(\u3b73-C3H5)]

G. Ciani
A. Sironi
P. Chini
A. Ceriotti
S. Martinengo

January 1980

The anion [Rh6(CO)14(CP3H5]-, obtained by reaction of [Rh6(CO)15]2- with allyl chloride, contains an...

A high nuclearity carbonyl cluster of rhenium stabilized by an interstitial carbide; synthesis and x-ray crystal structure of the anion [Re7C(CO)21]3

G. Ciani
G. D'Alfonso
M. Freni
P. Romiti
A. Sironi

January 1982

The trianion [Re7C(CO)21]3-, isolated from the pyrolysis of [ReH2(CO)4][NEt4] in n-tetradecane, has ...

A new high nuclearity cobalt nitrido-carbonyl cluster. Synthesis and crystal structure of the anion [Co14N3(CO)26]3

S. Martinengo
G. Ciani
A. Sironi

January 1988

The high nuclearity anion [Co14N13(CO)26]3-, obtained by pyrolysis in diglyme of the trigonal prisma...

New High-Nuclearity Carbonyl and Carbonyl-Substituted Rhodium Clusters and Their Relationships with Polyicosahedral Carbonyl-Substituted Palladium- and Gold-Thiolates

Dmitriy S. Dolzhnikov (1510894)
Maria C. Iapalucci (2028250)
Giuliano Longoni (1750657)
Cristina Tiozzo (1404871)
Stefano Zacchini (1431607)
Cristina Femoni (1692355)

November 2012

A reinvestigation of the synthesis of [H5–nRh13(CO)24]<...

Hexagonal close packing of metal atoms in the new polynuclear anions [Rh13(CO)24H5-n]n- (n=2 or 3); x-ray structure of [(Ph3P)2N]2[Rh13(CO)24H3].

V.G.Albano
A.Ceriotti
P.Chini
G.Ciani
S.Martinengo
W.M.Anker

January 1975

The [Rh13(CO)24H5-n]n- (n = 2 or 3) anions have been isolated from the reaction of the [Rh12(CO) 30]...

SYNTHESIS OF 2 NOVEL PENTANUCLEAR RHODIUM CLUSTERS BEARING THE ALKYL-LIKE LIGANDS CH2COOME AND CH2CN - X-RAY STRUCTURE OF [PPH4]2[RH5(MU-CO)6(CO)8(CH2CN)]

F. RAGAINI
F. PORTA
A. FUMAGALLI
F. DEMARTIN

January 1991

The reaction of [PPh4][Rh(CO)4] (1) under CO with BrCH2COOMe or BrCH2CN in a 5:3 molar ratio gave hi...

Synthesis, X-ray crystal structure and 13C NMR study of the anion [Re6(\u3bc3-H)2C(CO)18]2-: The first octahedral carbonyl cluster of rhenium

G. Ciani
G. D'Alfonso
P. Romiti
A. Sironi
M. Freni

January 1983

The novel high nuclearity carbido-carbonyl anion [Re6(\u3bc3-H)2C(CO)18]2-, isolated from the pyroly...

A novel high-nuclearity rhodium carbonyl cluster compound containing two interstitial nitrogen atoms : Synthesis and X-ray structure of the anion [Rh 14N2(CO)25]2

Abstract

Extracted data

A novel high-nuclearity rhodium carbonyl cluster compound containing two interstitial nitrogen atoms : Synthesis and X-ray structure of the anion [Rh 14N2(CO)25]2

Abstract

Extracted data

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