The reactions of [H4Re4(CO)15]2- with ethanolic I2 gives the novel species [H4Re4(CO)15I]-, characterized by IR, NMR and X-ray analysis. The monoanion contains an open tetrametal array as in the parent species, with the iodide ligand terminally bound to the apical metal atom. The hydridic hydrogen atoms are bridging on the four ReRe bonds. \ua9 1979
The reaction of the anion [Re4(\u3bc-H)6(CO) 12]2- with acids affords the unsaturated (58 valence el...
The compound (Me3BzN)2[H6Re4(CO)12] (Bz = benzyl) crystallizes in the monoclinic space group P21 c w...
The unsaturated anion [Re3(\u3bc-H)4(CO)10]- has been synthesized by reaction of [Re3(\u3bc-H)2(CO)1...
The novel anion [Re3H3I(CO)11]- has been obtained by reaction of ethanolic I2 solutions with either ...
The novel hydridocarbonyl cluster compound (NEt4)[H4Re3(CO)10] has been characterized by IR, NMR and...
The synthesis of the novel compound (NEt4)2 [H4Re4(CO)13] and its characterization by IR, NMR and X-...
The synthesis of the new anions [H3Re3(CO)10]2- and [H3Re3(\u3bc3-O)(CO)9]2-, obtained from [H4Re4(C...
The elusive mono-hydride tri-anion [HRu4(CO)12]3− (4) has been isolated and fully characterized for ...
The pyrolyses of [NEt4][H2Re(CO)4] in boiling n-heptane, n-octane and n-nonane are described. Mixtur...
The addition of [Re2H(CO)9]- to the electronically unsaturated complex [Re2(\u3bc-H)2(CO)8] rapidly ...
[[abstract]]The reaction between H4Re4(CO)(12) and N,N-dimethylformamide (DMF) in chloroform yields ...
The novel anions [Re3H3(\u3bc3-OR)(CO)9]- (R = Et, i-Pr, t-Bu) have been obtained by reaction of the...
Treatment of [H3Re3(CO)10](NEt4)2 (I) with acids gives [H4Re3(CO)10](NEt4) (II) which is unsaturated...
The reactions of the unsaturated anion [Re3(M-H)4(CO)10] with iodine have been investigated in vario...
The reaction between [Re3(\u3bc-H)3(CO)10(NCMe)2] and [ReH2(CO)4]- affords the novel hydridocarbonyl...
The reaction of the anion [Re4(\u3bc-H)6(CO) 12]2- with acids affords the unsaturated (58 valence el...
The compound (Me3BzN)2[H6Re4(CO)12] (Bz = benzyl) crystallizes in the monoclinic space group P21 c w...
The unsaturated anion [Re3(\u3bc-H)4(CO)10]- has been synthesized by reaction of [Re3(\u3bc-H)2(CO)1...
The novel anion [Re3H3I(CO)11]- has been obtained by reaction of ethanolic I2 solutions with either ...
The novel hydridocarbonyl cluster compound (NEt4)[H4Re3(CO)10] has been characterized by IR, NMR and...
The synthesis of the novel compound (NEt4)2 [H4Re4(CO)13] and its characterization by IR, NMR and X-...
The synthesis of the new anions [H3Re3(CO)10]2- and [H3Re3(\u3bc3-O)(CO)9]2-, obtained from [H4Re4(C...
The elusive mono-hydride tri-anion [HRu4(CO)12]3− (4) has been isolated and fully characterized for ...
The pyrolyses of [NEt4][H2Re(CO)4] in boiling n-heptane, n-octane and n-nonane are described. Mixtur...
The addition of [Re2H(CO)9]- to the electronically unsaturated complex [Re2(\u3bc-H)2(CO)8] rapidly ...
[[abstract]]The reaction between H4Re4(CO)(12) and N,N-dimethylformamide (DMF) in chloroform yields ...
The novel anions [Re3H3(\u3bc3-OR)(CO)9]- (R = Et, i-Pr, t-Bu) have been obtained by reaction of the...
Treatment of [H3Re3(CO)10](NEt4)2 (I) with acids gives [H4Re3(CO)10](NEt4) (II) which is unsaturated...
The reactions of the unsaturated anion [Re3(M-H)4(CO)10] with iodine have been investigated in vario...
The reaction between [Re3(\u3bc-H)3(CO)10(NCMe)2] and [ReH2(CO)4]- affords the novel hydridocarbonyl...
The reaction of the anion [Re4(\u3bc-H)6(CO) 12]2- with acids affords the unsaturated (58 valence el...
The compound (Me3BzN)2[H6Re4(CO)12] (Bz = benzyl) crystallizes in the monoclinic space group P21 c w...
The unsaturated anion [Re3(\u3bc-H)4(CO)10]- has been synthesized by reaction of [Re3(\u3bc-H)2(CO)1...