(R)- and (S)-2-methyldecan-1-ol 3a has been prepared in > 98% enantiomeric excess (ee) by transesterification with vinyl acetate in chloroform in the presence of Pseudomonas fluorescens lipase. Oxidation of the alcohol 3a affords nearly optically pure 2-methyldecanoic acid 3b
The two enantiomers of Iopanoic acid 1 were prepared in enantiomeric excess higher than 90\% by e...
The enzymatic kinetic resolution (EKR) of racemic alcohols or esters is a broadly recognized methodo...
Enantiomerically pure 4-methyl-tetrahydro-5-oxo-2-furancarboxylic acids and esters are prepared by e...
Lipase-catalyzed transesterification of 2-methyl-1,3-propanediol 1 in chloroform affords enantiomeri...
The irreversible transesterification of racemic 2-methyl-1,3-propanediol derivatives, the monoethers...
Enzyme catalyzed transesterification of rac-2-chloro-1-(2-furyl)ethanol rac-1 using vinyl acetate af...
Enantiomerically pure (R)- and (S)-epoxyalcohols 1, chiral intermediates for the synthesis of (R)- a...
The Pseudomonas fluorescens (P. cepacia) lipase-catalyzed irreversible transesterification of 2-phen...
meso-exo-3,5-dihydroxymethylenetricyclo[5.2.1.0(2,6)]decane was efficiently desymmetrized by the lip...
Primary alcohols containing at the \u3b1-carbon small groups such as methyl or an oxirane ring are e...
(R)-(+)-Paraconic acid 4, (S)-(-)-terebic acid 6 and their corresponding methyl and ethyl esters hav...
The transesterification of 2-substituted-1,4-butanediols 1a, 2a and 3a with vinyl acetate catalyzed ...
Enzymes as tools in organic synthesis have provided enormous advantages. This thesis deals with the ...
Two different chemoenzymatic approaches allowed the preparation of the enantiomers of desoxymusca...
A dessimetrização mais eficiente do composto meso-exo-3,5-dihidroximetilenotriciclo[ 5.2.1.02,6]deca...
The two enantiomers of Iopanoic acid 1 were prepared in enantiomeric excess higher than 90\% by e...
The enzymatic kinetic resolution (EKR) of racemic alcohols or esters is a broadly recognized methodo...
Enantiomerically pure 4-methyl-tetrahydro-5-oxo-2-furancarboxylic acids and esters are prepared by e...
Lipase-catalyzed transesterification of 2-methyl-1,3-propanediol 1 in chloroform affords enantiomeri...
The irreversible transesterification of racemic 2-methyl-1,3-propanediol derivatives, the monoethers...
Enzyme catalyzed transesterification of rac-2-chloro-1-(2-furyl)ethanol rac-1 using vinyl acetate af...
Enantiomerically pure (R)- and (S)-epoxyalcohols 1, chiral intermediates for the synthesis of (R)- a...
The Pseudomonas fluorescens (P. cepacia) lipase-catalyzed irreversible transesterification of 2-phen...
meso-exo-3,5-dihydroxymethylenetricyclo[5.2.1.0(2,6)]decane was efficiently desymmetrized by the lip...
Primary alcohols containing at the \u3b1-carbon small groups such as methyl or an oxirane ring are e...
(R)-(+)-Paraconic acid 4, (S)-(-)-terebic acid 6 and their corresponding methyl and ethyl esters hav...
The transesterification of 2-substituted-1,4-butanediols 1a, 2a and 3a with vinyl acetate catalyzed ...
Enzymes as tools in organic synthesis have provided enormous advantages. This thesis deals with the ...
Two different chemoenzymatic approaches allowed the preparation of the enantiomers of desoxymusca...
A dessimetrização mais eficiente do composto meso-exo-3,5-dihidroximetilenotriciclo[ 5.2.1.02,6]deca...
The two enantiomers of Iopanoic acid 1 were prepared in enantiomeric excess higher than 90\% by e...
The enzymatic kinetic resolution (EKR) of racemic alcohols or esters is a broadly recognized methodo...
Enantiomerically pure 4-methyl-tetrahydro-5-oxo-2-furancarboxylic acids and esters are prepared by e...