Fluoride effect on the palladium-phenanthroline catalyzed carbonylation of nitroarenes to carbamates

GASPERINI, MICHELA BARBARA
F. Ragaini
S. Cenini
E. Gallo
S. Fantauzzi

Open link

Publication date

January 2007

DOI

10.1002/aoc.1292

Publisher

Wiley

Abstract

Fluorides promote the palladium-phenanthroline catalyzed carbonylation of nitroarenes to carbamates. The effect is more evident on the rate of the reaction at short reaction times, but a positive effect on selectivity is also observed under certain conditions. The effect is observed even under conditions under which chloride inhibits the reaction. Tetraethylammonium is a better countercation than sodium

Extracted data

M. Gasperini
C. Remondini
F. Ragaini
A. Caselli
S. Cenini

January 2005

The application of the palladiurn-phenanthroline catalytic system to the carbonylation of nitrobenze...

Mechanistic study of the Ru-3(CO)(12)/chloride catalyzed carbonylation reactions of nitroarenes to carbamates and ureas; the role of the alkylammonium cation

F. Ragaini
S. Cenini

January 2000

The effect of the chloride countercation on the mechanism of the Ru-3(CO)(12)/chloride catalyzed car...

Mechanistic studies of palladium-catalysed carbonylation reactions of nitro compounds to isocyanates, carbamates and ureas

F. Ragaini
S. Cenini

January 1996

Many different palladium-based catalytic systems have been reported for the carbonylation reactions ...

Metal fluoride promoted catalytic hydrogenation of aromatic nitro compounds over RANEY (R) Ni

Liu, Xia
Ma, Xuanxuan
Liu, Sujing
Liu, Ying
Xia, Chuanhai
Liu, Y (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Biol & Biol Resources Utilizat, 17 Chunhui Rd, Yantai 264003, Peoples R China. yliu@yic.ac.cn
chxia@yic.ac.cn

January 2015

The catalytic hydrogenation reactivity of aromatic nitro compounds over RANEY (R) Ni was substantial...