Photovoltaic Characteristics of a Dye-Sensitized Solar Cell (DSSC) Fabricated by a Nano-Particle Deposition System (NPDS)

Nano particle deposition system (NPDS) was evaluated for the potential photoelectrode fabrication method for dye-sensitized solar cell (DSSC). TiO2 powders as a photoelectrode for DSSC, were fabricated via NPDS and screen printing methods to compare its photovoltaic characteristics. The NPDS is a novel system for depositing ceramic and metallic powders on substrates at room temperature without using solvents by accelerating particles to supersonic velocity. The conventional method for preparing working electrodes uses TiO2 paste where poor adhesion to the substrate and numerous steps to properly disperse the powders are the main problems. To overcome these issues, TiO2 powders were directly sprayed onto ITO glass using the NPDS. The nano-sized TiO2 particles were densely deposited, no adhesion problems were noted and the solar-cell properties were improved. The photovoltaic performance of a cell having TiO2 layers first deposited by the NPDS method and then deposited by the paste method was compared to a cell fabricated only using the NPDS and only using the paste. A light conversion efficiency of 3.5% was obtained for the former cell, which indicates synergy effect of using these two methods. The screen-printing step right after NPDS deposition served to densify the TiO2 film, which decreased the series resistance. Therefore, NPDS was found to be a promising approach for improving DSSC properties and efficiencies.This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (NRF-2012R1A1A3004290), by a National Research Foundation of Korea (NRF) grant funded by the Korean government (MEST) (No. 2011-0029862) and by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MEST) (No. 2012047189)