XAS characterisation of xenon bubbles in uranium dioxide

International audienceX-ray absorption spectroscopy experiments were performed on a set of uranium dioxide samples implanted with 1017 xenon cm−2 at 800 keV (8 at.% at 140 nm). EXAFS measurements performed at 12 K showed that during implantation the gas forms highly pressurised nanometre size inclusions. Bubble pressures were estimated at 2.8 ± 0.3 GPa at low temperature. Following the low energy xenon implantation, samples were annealed between 1073 and 1773 K for several hours. Stability of nanometre size highly pressurized xenon aggregates in UO2 is demonstrated up to 1073 K as for this temperature almost no modification of the xenon environment was observed. Above this temperature, bubbles will trap migrating vacancies and their inner pressure is seen to decrease substantially