Add to ORKGThe substitution reactions of [Rh(COD)2][BArF4] with PNP and PONOP pincer ligands 2,6-bis(di-tert-butylphosphinomethyl)pyridine and 2,6-bis(di-tert-butylphosphinito)pyridine in the weakly coordinating solvent 1,2-F2C6H4 are shown to be an operationally simple method for the generation of reactive formally 14 VE rhodium(I) adducts in solution. Application of this methodology enables synthesis of known adducts of CO, N2, H2, previously unknown water complexes, and novel vinylidene derivatives [Rh(pincer)(CCHR)][BArF4] (R = tBu, 3,5-tBu2C6H3), through reversible reactions with terminal alkynes
Reactions of the aryl complexes Rh(aryl){3-P, O, P-[xant(PiPr2)2]} (1; aryl = 3, 5-Me2C6H3 (a), C6H5...
Reactions of the aryl complexes Rh(aryl){3-P, O, P-[xant(PiPr2)2]} (1; aryl = 3, 5-Me2C6H3 (a), C6H5...
The manuscript reports the synthesis, characterization, and analysis of electronic structure in a se...
Through use of a bespoke macrocyclic variant, we demonstrate a novel approach for tuning the reactiv...
The synthesis of macrocyclic variants of commonly employed phosphine-based pincer ligands derived fr...
The synthesis of macrocyclic variants of commonly employed phosphine-based pincer ligands derived fr...
The synthesis of macrocyclic variants of commonly employed phosphine-based pincer ligands derived fr...
Straightforward procedures for the generation of rhodium(I) κCl–chlorocarbon complexes of the form [...
By use of a macrocyclic phosphinite pincer ligand and bulky substrate substituents, we demonstrate h...
By use of a macrocyclic phosphinite pincer ligand and bulky substrate substituents, we demonstrate h...
By use of a macrocyclic phosphinite pincer ligand and bulky substrate substituents, we demonstrate h...
Having recently reported on the synthesis and rhodium complexes of the novel macrocyclic pincer liga...
Having recently reported on the synthesis and rhodium complexes of the novel macrocyclic pincer liga...
An expedient new route to the cationic [(PNPtBu)Rh(L)] + metal fragments (PNPtBu = κ3-NC 5H3-2,6-(CH...
Rigid mer-tridentate ‘pincer’ ligands are a prominent ligand class in organometallic chemistry and c...
Reactions of the aryl complexes Rh(aryl){3-P, O, P-[xant(PiPr2)2]} (1; aryl = 3, 5-Me2C6H3 (a), C6H5...
Reactions of the aryl complexes Rh(aryl){3-P, O, P-[xant(PiPr2)2]} (1; aryl = 3, 5-Me2C6H3 (a), C6H5...
The manuscript reports the synthesis, characterization, and analysis of electronic structure in a se...
Through use of a bespoke macrocyclic variant, we demonstrate a novel approach for tuning the reactiv...
The synthesis of macrocyclic variants of commonly employed phosphine-based pincer ligands derived fr...
The synthesis of macrocyclic variants of commonly employed phosphine-based pincer ligands derived fr...
The synthesis of macrocyclic variants of commonly employed phosphine-based pincer ligands derived fr...
Straightforward procedures for the generation of rhodium(I) κCl–chlorocarbon complexes of the form [...
By use of a macrocyclic phosphinite pincer ligand and bulky substrate substituents, we demonstrate h...
By use of a macrocyclic phosphinite pincer ligand and bulky substrate substituents, we demonstrate h...
By use of a macrocyclic phosphinite pincer ligand and bulky substrate substituents, we demonstrate h...
Having recently reported on the synthesis and rhodium complexes of the novel macrocyclic pincer liga...
Having recently reported on the synthesis and rhodium complexes of the novel macrocyclic pincer liga...
An expedient new route to the cationic [(PNPtBu)Rh(L)] + metal fragments (PNPtBu = κ3-NC 5H3-2,6-(CH...
Rigid mer-tridentate ‘pincer’ ligands are a prominent ligand class in organometallic chemistry and c...
Reactions of the aryl complexes Rh(aryl){3-P, O, P-[xant(PiPr2)2]} (1; aryl = 3, 5-Me2C6H3 (a), C6H5...
Reactions of the aryl complexes Rh(aryl){3-P, O, P-[xant(PiPr2)2]} (1; aryl = 3, 5-Me2C6H3 (a), C6H5...
The manuscript reports the synthesis, characterization, and analysis of electronic structure in a se...