N-Adamantylimidoylketene 2 produced from pyrroledione 1 is in thermal equilibrium with azetin-2-one 4; 2 also thermally rearranges to oxoketenimine 3; azetin-2-one 4 is photolytically converted into imidoylketene 2, and thermally cleaved to adamantyl isocyanate 5 and 1-phenylpropyne 6
We have found that, while 2-oxetanone undergoes thermal decarboxylation at 350 degrees C to give CO2...
2,3-Dihydropyrrole-2,3-diones 1 thermally extrude CO, giving imidoylketenes 2, which cyclise efficie...
Cyanoketene (8) is generated in high yields on flash vacuum thermolysis (FVT) of suitably substitute...
First published as an Advance Article on the web 4th November 2004 FVT of pyrroledione 10 affords th...
Thermal CO extrusion from 2,3-dihydropyrrole-2,3-dione 3 generates imidoylketene 4, which cyclizes t...
Polyfunctional building blocks are essential for the implementation of diversity-oriented synthetic ...
FVP of triazole 13 produces the isolable ketenimine 11 together with indole 15. 11 undergoes reversi...
Methyleneketenes 2 and imidoylketenes 4, generated from Meldrum's acid derivatives 1 and 2,3-dihydro...
Flash vacuum thermolysis (FVT) of 1-methyl-5-phenyltetrazole (5b), 2-methyl-5-phenyltetrazole (1b), ...
Flash vacuum thermolysis (FVT) of 1-methyl-5-phenyltetrazole (<b>5b</b>), 2-methyl-5-phenyltetrazole...
The novel iminopropadienones RN=C=C=C=O (8) and the corresponding thione 21 have been synthesized by...
The energy surface connecting oxazinium olates 9, several possible conformers of ketenes 10 and 11, ...
Flash vacuum pyrolyses or pulsed pyrolysis of azole esters 1b and 20 and their carboxylic acids la a...
alpha-Oxoketenes (RCO-CR'=C=O) undergo a degenerate thermal rearrangement by a 1,3-shift of the acyl...
Theoretical calculations (B3LYP/6-311+G(3df,2p)//B3LYP/6-31G*) of the 1,3 migration of NR2 transform...
We have found that, while 2-oxetanone undergoes thermal decarboxylation at 350 degrees C to give CO2...
2,3-Dihydropyrrole-2,3-diones 1 thermally extrude CO, giving imidoylketenes 2, which cyclise efficie...
Cyanoketene (8) is generated in high yields on flash vacuum thermolysis (FVT) of suitably substitute...
First published as an Advance Article on the web 4th November 2004 FVT of pyrroledione 10 affords th...
Thermal CO extrusion from 2,3-dihydropyrrole-2,3-dione 3 generates imidoylketene 4, which cyclizes t...
Polyfunctional building blocks are essential for the implementation of diversity-oriented synthetic ...
FVP of triazole 13 produces the isolable ketenimine 11 together with indole 15. 11 undergoes reversi...
Methyleneketenes 2 and imidoylketenes 4, generated from Meldrum's acid derivatives 1 and 2,3-dihydro...
Flash vacuum thermolysis (FVT) of 1-methyl-5-phenyltetrazole (5b), 2-methyl-5-phenyltetrazole (1b), ...
Flash vacuum thermolysis (FVT) of 1-methyl-5-phenyltetrazole (<b>5b</b>), 2-methyl-5-phenyltetrazole...
The novel iminopropadienones RN=C=C=C=O (8) and the corresponding thione 21 have been synthesized by...
The energy surface connecting oxazinium olates 9, several possible conformers of ketenes 10 and 11, ...
Flash vacuum pyrolyses or pulsed pyrolysis of azole esters 1b and 20 and their carboxylic acids la a...
alpha-Oxoketenes (RCO-CR'=C=O) undergo a degenerate thermal rearrangement by a 1,3-shift of the acyl...
Theoretical calculations (B3LYP/6-311+G(3df,2p)//B3LYP/6-31G*) of the 1,3 migration of NR2 transform...
We have found that, while 2-oxetanone undergoes thermal decarboxylation at 350 degrees C to give CO2...
2,3-Dihydropyrrole-2,3-diones 1 thermally extrude CO, giving imidoylketenes 2, which cyclise efficie...
Cyanoketene (8) is generated in high yields on flash vacuum thermolysis (FVT) of suitably substitute...
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