Directed synthesis of {Mn<sub>18</sub>Cu<sub>6</sub>} heterometallic complexes
- Milway, Victoria A.
- Tuna, Floriana
- Farrell, Andrew R.
- Sharp, Laura E.
- Parsons, Simon
- Murrie, Mark
DOIAbstract
A two-step method for the directed synthesis of high-nuclearity Mn<sup>III</sup>-Mn<sup>II</sup>-Cu<sup>II</sup> heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core
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