[(Z)-O-Isopropyl N-(m-tolyl) thiocarbamato-kappa S](tricyclohexylphosphine-kappa P)gold(I)

The Au atom in the title compound, [Au(C(11)H(14)NOS)-(C(18)H(33)P)], is coordinated within an S, P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73 (3)degrees], with the distortion due in part to a close intramolecular Au center dot center dot center dot O contact [3.060 (3) angstrom]. In the crystal structure, molecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H center dot center dot center dot pi