Protective ligands are key components of ligand‐protected metal nanoclusters (NCs), as they offer good stability and multiple functionalities to the metal NCs in solution. Herein, we demonstrated that the ligand landscape on the NC surface could also be used to modulate the catalytic active sites of metal NCs in solution thus to direct the catalytic reaction towards desirable products through a different pathway. We found that thiolate ligands, namely, p‐mercaptobenzoic acid (p‐MBA), in Au25(p‐MBA)18 NCs could influence the reaction pathway in the catalytic hydrogenation of 4‐nitrophenol in solution. In particular, the well‐defined ligand structure of Au25(p‐MBA)18 NCs in solution provided a unique environment for the coadsorption of two su...
To explore the electronic and catalytic properties of nanoclusters, here we report an aromatic-thiol...
Metal nanoclusters whose surface ligands are removable while keeping their metal framework structure...
Chemoselective hydrogenation of 3-nitrostyrene to 3-vinylaniline is quite challenging because of com...
Protective ligands are key components of ligand-protected metal nanoclusters (NCs), as they offer g...
In this work, the effects of thiolate ligands (-SR, e.g., chain length and functional moiety) on th...
Quasi-homogeneous ligand-protected gold nanoclusters (Au NCs) with atomic precision and well-defined...
In this work, the effects of thiolate ligands (-SR, e.g., chain length and functional moiety) on t...
Quasi-homogeneous ligand-protected gold nanoclusters (Au NCs) with atomic precision and welldefined ...
A trio of thiolate-protected atomically precise gold nanoclusters, [Au23(S-c-C6H11)16]–, Au24(SCH2pH...
AbstractA trio of thiolate-protected atomically precise gold nanoclusters, [Au23(S-c-C6H11)16]–, Au2...
We investigate the catalytic properties of water-soluble Au<sub><i>n</i></sub>(SG)<sub><i>m</i></sub...
To explore the electronic and catalytic properties of nanoclusters, here we report an aromatic-thiol...
The hydrogenation of nitro compounds is an industrial process that has experienced a renovated inter...
Chemoselective hydrogenation of nitrobenzaldehyde derivatives is one of the important catalytic proc...
The hydrogenation of nitro compounds is an industrial process that has experienced a renovated inter...
To explore the electronic and catalytic properties of nanoclusters, here we report an aromatic-thiol...
Metal nanoclusters whose surface ligands are removable while keeping their metal framework structure...
Chemoselective hydrogenation of 3-nitrostyrene to 3-vinylaniline is quite challenging because of com...
Protective ligands are key components of ligand-protected metal nanoclusters (NCs), as they offer g...
In this work, the effects of thiolate ligands (-SR, e.g., chain length and functional moiety) on th...
Quasi-homogeneous ligand-protected gold nanoclusters (Au NCs) with atomic precision and well-defined...
In this work, the effects of thiolate ligands (-SR, e.g., chain length and functional moiety) on t...
Quasi-homogeneous ligand-protected gold nanoclusters (Au NCs) with atomic precision and welldefined ...
A trio of thiolate-protected atomically precise gold nanoclusters, [Au23(S-c-C6H11)16]–, Au24(SCH2pH...
AbstractA trio of thiolate-protected atomically precise gold nanoclusters, [Au23(S-c-C6H11)16]–, Au2...
We investigate the catalytic properties of water-soluble Au<sub><i>n</i></sub>(SG)<sub><i>m</i></sub...
To explore the electronic and catalytic properties of nanoclusters, here we report an aromatic-thiol...
The hydrogenation of nitro compounds is an industrial process that has experienced a renovated inter...
Chemoselective hydrogenation of nitrobenzaldehyde derivatives is one of the important catalytic proc...
The hydrogenation of nitro compounds is an industrial process that has experienced a renovated inter...
To explore the electronic and catalytic properties of nanoclusters, here we report an aromatic-thiol...
Metal nanoclusters whose surface ligands are removable while keeping their metal framework structure...
Chemoselective hydrogenation of 3-nitrostyrene to 3-vinylaniline is quite challenging because of com...