Add to ORKGThermal activation of gamma,delta-unsaturated ketones (1, 9 and 12) in the presence of a catalytic amount of propionic acid causes a rearrangement to give new gamma,delta-unsaturated ketones (2, 10 and 14) via an intramolecular ene reaction followed by a retro-ene reaction
The ketol 3a̲ and its acetate 3b̲ when refluxed in methanolic potassium hydroxide (5%) were found to...
Acetone is the expected ketone product of an acetic acid decarboxylative ketonization reaction with ...
Developing olefin isomerization reactions to reach kinetically controlled Z-alkenes is challenging b...
Mercuric acetate mediated isomerisation of primary propargyl alcohols to vinyl ketones analagous to ...
Acid-catalysed thermal rearrangement of 4-aryl-4-methylhex-5-en-2-ones (products of the Claisen rear...
The hydroxy enones 5a, 5b, 5c, 4d, 4a and 4b rearrange when treated with aqueous alkali to the dione...
The mechanism of rearrangement of 1-(substituted phenyl)-1,3-dimethoxy-2-propanones to give substitu...
The title compounds (1a-e̲) undergo facile base catalysed rearrangement to give 5a-e̲ ...
Low temperature Lewis acid catalysed oxygen to carbon rearrangements of anomerically linked 6-substi...
Protonation by gaseous H+3, CnH+5 (n=1,2), s-C3H+7 and t-C4H+9 cations promotes rearrangement of cyc...
Mattay J. BETA-OXA-GAMMA,DELTA-ENONES, .2. REARRANGEMENT AND INTRAMOLECULAR CYCLOADDITION OF 1-CYCLO...
The acid-catalyzed condensation of $(E)$-triethyl orthocrotonate, (Z)-triethyl orthocrotonate, and t...
We report a new catalytic protocol for the synthesis of gamma,delta-unsaturated carbonyl units from ...
We report a new catalytic protocol for the synthesis of gamma,delta-unsaturated carbonyl units from ...
The rearrangement of trans-pinonic acid into homoterpenyl methyl ketone has been studied in order to...
The ketol 3a̲ and its acetate 3b̲ when refluxed in methanolic potassium hydroxide (5%) were found to...
Acetone is the expected ketone product of an acetic acid decarboxylative ketonization reaction with ...
Developing olefin isomerization reactions to reach kinetically controlled Z-alkenes is challenging b...
Mercuric acetate mediated isomerisation of primary propargyl alcohols to vinyl ketones analagous to ...
Acid-catalysed thermal rearrangement of 4-aryl-4-methylhex-5-en-2-ones (products of the Claisen rear...
The hydroxy enones 5a, 5b, 5c, 4d, 4a and 4b rearrange when treated with aqueous alkali to the dione...
The mechanism of rearrangement of 1-(substituted phenyl)-1,3-dimethoxy-2-propanones to give substitu...
The title compounds (1a-e̲) undergo facile base catalysed rearrangement to give 5a-e̲ ...
Low temperature Lewis acid catalysed oxygen to carbon rearrangements of anomerically linked 6-substi...
Protonation by gaseous H+3, CnH+5 (n=1,2), s-C3H+7 and t-C4H+9 cations promotes rearrangement of cyc...
Mattay J. BETA-OXA-GAMMA,DELTA-ENONES, .2. REARRANGEMENT AND INTRAMOLECULAR CYCLOADDITION OF 1-CYCLO...
The acid-catalyzed condensation of $(E)$-triethyl orthocrotonate, (Z)-triethyl orthocrotonate, and t...
We report a new catalytic protocol for the synthesis of gamma,delta-unsaturated carbonyl units from ...
We report a new catalytic protocol for the synthesis of gamma,delta-unsaturated carbonyl units from ...
The rearrangement of trans-pinonic acid into homoterpenyl methyl ketone has been studied in order to...
The ketol 3a̲ and its acetate 3b̲ when refluxed in methanolic potassium hydroxide (5%) were found to...
Acetone is the expected ketone product of an acetic acid decarboxylative ketonization reaction with ...
Developing olefin isomerization reactions to reach kinetically controlled Z-alkenes is challenging b...