Add to ORKGEnantiospecific total synthesis of optical antipode of the sesquiterpene 5-senecioyloxy-10,11-epoxythapsan-10-ol has been described. (R)-Carvone has been employed as the chiral starting material and a combination of intramolecular alkyation and Criegee fragmentation are employed for intramolecular stereospecific transfer of the chirality. An intramolecular diazoketone cyclopropanation and regioselective cyclopropane ring cleavage reactions have been employed or the creation of the three requisite contiguous quaternary carbon atoms
Enantiospecific synthesis of both enantiomers of the marine sesquiterpene 2-thiocyanatoneopupukeanan...
Synthesis of the chiral bicyclic ketone mentioned in the title starting from R-carvone, and its elab...
Synthesis of the chiral bicyclic ketone mentioned in the title starting from R-carvone, and its elab...
First enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxythapsan-...
413-422First enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxytha...
776-788Enantiospecific total synthesis of optical antipode of the sesquiterpene 5-senecioyloxy-10,1...
Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small group of...
449-459Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small g...
The enantiospecific first total synthesis of 10-hydroxy-10,11-epoxythapsan-5-yl senecioate (+)-1f, t...
1029-1039Enantiospecific synthesis of 3-thapsenol, comprising the carbon framework of a small group...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
An enantiospecific synthesis of a thapsane containing an oxygen substituent at the C-3 position is a...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
Enantiospecific synthesis of the sesquiterpenes pacifigorgianes has been described. (R)-Carvone has ...
Enantiospecific synthesis of both enantiomers of the marine sesquiterpene 2-thiocyanatoneopupukeanan...
Synthesis of the chiral bicyclic ketone mentioned in the title starting from R-carvone, and its elab...
Synthesis of the chiral bicyclic ketone mentioned in the title starting from R-carvone, and its elab...
First enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxythapsan-...
413-422First enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxytha...
776-788Enantiospecific total synthesis of optical antipode of the sesquiterpene 5-senecioyloxy-10,1...
Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small group of...
449-459Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small g...
The enantiospecific first total synthesis of 10-hydroxy-10,11-epoxythapsan-5-yl senecioate (+)-1f, t...
1029-1039Enantiospecific synthesis of 3-thapsenol, comprising the carbon framework of a small group...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
An enantiospecific synthesis of a thapsane containing an oxygen substituent at the C-3 position is a...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
Enantiospecific synthesis of the sesquiterpenes pacifigorgianes has been described. (R)-Carvone has ...
Enantiospecific synthesis of both enantiomers of the marine sesquiterpene 2-thiocyanatoneopupukeanan...
Synthesis of the chiral bicyclic ketone mentioned in the title starting from R-carvone, and its elab...
Synthesis of the chiral bicyclic ketone mentioned in the title starting from R-carvone, and its elab...