The polymerization of methyl methacrylate initiated by a mixed ligand complex. [NN-ethylenebis(salicylideneiminato)](benzoylacetonato)cobalt(III) has been studied in bulk and in benzene at 70° and 80°. The rate of polymerization is proportional to (concentration of the chelate)Image and the monomer exponent is close to 1.5. The activation energy and the kinetic and transfer constants are evaluated. A free radical mechanism has been proposed
This work reveals the preponderance of an intramolecular metal chelation phenomenon in a controlled ...
We studied the kinetics and mechanism of the charge-transfer polymerization of methyl methacrylate (...
The polymerization of methyl methacrylate MMA catalyzed by [Mo(CO) 4L2] [L2 = diphenylphosphinometha...
The polymerization of methyl methacrylate initiated by a mixed ligand complex. [NN-ethylenebis(salic...
The polymerization of methyl methacrylate initiated by a mixed ligand complex. [NN′-ethylenebis(sali...
Polymerization of methyl methacrylate in the presence of a mixed ligand complex, [N,N-ethylenebis(sa...
A series of cobalt(II) phenoxy-imine complexes (CoII(FI)2) have been synthesized to mediate the radi...
International audienceThe complex [Co-II(tmhd)(2)] (4; tmhd=2,2,6,6-tetramethylhepta-3,5-dionato) ha...
Cobalt mediated radical polymerization (CMRP) of vinyl acetate (VAc) follows a reversible terminatio...
Cobalt mediated radical polymerization (CMRP) of vinyl acetate (VAc) follows a reversible terminatio...
International audienceThe complex [Co-II(tmhd)(2)] (4; tmhd=2,2,6,6-tetramethylhepta-3,5-dionato) ha...
The behavior of the chelate, ferric dipivaloylmethide, Fe(DPM)3, in vinyl polymerization systems was...
The behavior of the chelate, ferric dipivaloylmethide, Fe(DPM)3, in vinyl polymerization systems was...
The polymerization kinetics methyl methacrylate initiated by cobalt (II) 5-methyl-5-hexene-2,4-diona...
Two dinuclear cobalt complexes based on bis-diketonate ligands (ligand 1: 3,3'-(1,3-phenylene)bis(1-...
This work reveals the preponderance of an intramolecular metal chelation phenomenon in a controlled ...
We studied the kinetics and mechanism of the charge-transfer polymerization of methyl methacrylate (...
The polymerization of methyl methacrylate MMA catalyzed by [Mo(CO) 4L2] [L2 = diphenylphosphinometha...
The polymerization of methyl methacrylate initiated by a mixed ligand complex. [NN-ethylenebis(salic...
The polymerization of methyl methacrylate initiated by a mixed ligand complex. [NN′-ethylenebis(sali...
Polymerization of methyl methacrylate in the presence of a mixed ligand complex, [N,N-ethylenebis(sa...
A series of cobalt(II) phenoxy-imine complexes (CoII(FI)2) have been synthesized to mediate the radi...
International audienceThe complex [Co-II(tmhd)(2)] (4; tmhd=2,2,6,6-tetramethylhepta-3,5-dionato) ha...
Cobalt mediated radical polymerization (CMRP) of vinyl acetate (VAc) follows a reversible terminatio...
Cobalt mediated radical polymerization (CMRP) of vinyl acetate (VAc) follows a reversible terminatio...
International audienceThe complex [Co-II(tmhd)(2)] (4; tmhd=2,2,6,6-tetramethylhepta-3,5-dionato) ha...
The behavior of the chelate, ferric dipivaloylmethide, Fe(DPM)3, in vinyl polymerization systems was...
The behavior of the chelate, ferric dipivaloylmethide, Fe(DPM)3, in vinyl polymerization systems was...
The polymerization kinetics methyl methacrylate initiated by cobalt (II) 5-methyl-5-hexene-2,4-diona...
Two dinuclear cobalt complexes based on bis-diketonate ligands (ligand 1: 3,3'-(1,3-phenylene)bis(1-...
This work reveals the preponderance of an intramolecular metal chelation phenomenon in a controlled ...
We studied the kinetics and mechanism of the charge-transfer polymerization of methyl methacrylate (...
The polymerization of methyl methacrylate MMA catalyzed by [Mo(CO) 4L2] [L2 = diphenylphosphinometha...