Add to ORKGFirst enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxythapsan-10-ol has been described. (R)-Carvone has been employed as the chiral starting material and a combination of intramolecular alkylation and Criegee fragmentation are employed for intramolecular stereospecific transfer of the chirality. An\ud intramolecular diazoketone cyclopropanation and regioselective cyclopropane ring cleavage reactions have been employed for the creation of the three requisite contiguous quaternary carbon atoms
An enantiospecific approach to a functionalised carbon framework of the sesquiterpenes, cyperanes, s...
An enantiospecific formal total synthesis of (-)-ceratopicanol starting from the readily and abundan...
Stereo- and enantiospecific synthesis of (+)-valerane starting from R-carvone utilising orthoester C...
413-422First enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxytha...
Enantiospecific total synthesis of optical antipode of the sesquiterpene 5-senecioyloxy-10,11-epoxyt...
776-788Enantiospecific total synthesis of optical antipode of the sesquiterpene 5-senecioyloxy-10,1...
Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small group of...
449-459Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small g...
An enantiospecific synthesis of a thapsane containing an oxygen substituent at the C-3 position is a...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The enantiospecific first total synthesis of 10-hydroxy-10,11-epoxythapsan-5-yl senecioate (+)-1f, t...
1029-1039Enantiospecific synthesis of 3-thapsenol, comprising the carbon framework of a small group...
The first enantiospecific synthesis of (+)-cis,anti,cis-1,8,12,12-tetramethyl-4-oxatricyclo[6.4.0.02...
An enantiospecific approach to a functionalised carbon framework of the sesquiterpenes, cyperanes, s...
An enantiospecific formal total synthesis of (-)-ceratopicanol starting from the readily and abundan...
Stereo- and enantiospecific synthesis of (+)-valerane starting from R-carvone utilising orthoester C...
413-422First enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxytha...
Enantiospecific total synthesis of optical antipode of the sesquiterpene 5-senecioyloxy-10,11-epoxyt...
776-788Enantiospecific total synthesis of optical antipode of the sesquiterpene 5-senecioyloxy-10,1...
Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small group of...
449-459Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small g...
An enantiospecific synthesis of a thapsane containing an oxygen substituent at the C-3 position is a...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The enantiospecific first total synthesis of 10-hydroxy-10,11-epoxythapsan-5-yl senecioate (+)-1f, t...
1029-1039Enantiospecific synthesis of 3-thapsenol, comprising the carbon framework of a small group...
The first enantiospecific synthesis of (+)-cis,anti,cis-1,8,12,12-tetramethyl-4-oxatricyclo[6.4.0.02...
An enantiospecific approach to a functionalised carbon framework of the sesquiterpenes, cyperanes, s...
An enantiospecific formal total synthesis of (-)-ceratopicanol starting from the readily and abundan...
Stereo- and enantiospecific synthesis of (+)-valerane starting from R-carvone utilising orthoester C...