Add to ORKGAlkyl groups can be cleaved e.ciently and selectively from tertiary alkyl amines using propargyl chloroformate. The propargyloxycarbonyl (Poc) protected secondary amines thus obtained can be deblocked under neutral and mild conditions using benzyltriethylammonium tetrathiomolybdate. The generality and compatibility of the method have been studied with a wide range of functionalities
Treatment of a range of N-benzyl tertiary amines with aqueous eerie ammonium nitrate results in N-de...
N-Alkylation is conceptually the most straightforward disconnection towards secondary and tertiary a...
The invention relates to improved means and methods for N- dealkylation of alkylated amines. Provide...
Alkyl groups can be cleaved e.ciently and selectively from tertiary alkyl amines using propargyl chl...
N-dealkylation, the removal of an N-alkyl group from an amine, is an important chemical transformati...
A method for selective mono-N-alkylation of primary amines to produce secondary amines that are subs...
Direct preparation of tertiary amines in which two substituents are aromatic is described. In the pr...
The palladium-promoted deallylation of allylamines derived from primary and secondary amines is achi...
A novel and selective cascade reaction of primary amines and alkynes for the synthesis of the corres...
A series of competition experiments has revealed that selective cleavage of N-benzyl-protected secon...
A number of tertiary N-allyl- and N-propargyl-substituted amines have been prepared by alkylation of...
The first highly effective Pd/C-catalyzed oxidative <i>N</i>-dealkylation/carbonylation of various a...
Propargyloxycarbonyl chloride, 1, has been used to protect the hydroxyl and amino functionalities of...
Propargyloxycarbonyl chloride, 1, has been used to protect the hydroxyl and amino functionalities of...
ZnBr2 in dichloromethane is a convenient reagent for mild and selective removal of the tert-butoxyca...
Treatment of a range of N-benzyl tertiary amines with aqueous eerie ammonium nitrate results in N-de...
N-Alkylation is conceptually the most straightforward disconnection towards secondary and tertiary a...
The invention relates to improved means and methods for N- dealkylation of alkylated amines. Provide...
Alkyl groups can be cleaved e.ciently and selectively from tertiary alkyl amines using propargyl chl...
N-dealkylation, the removal of an N-alkyl group from an amine, is an important chemical transformati...
A method for selective mono-N-alkylation of primary amines to produce secondary amines that are subs...
Direct preparation of tertiary amines in which two substituents are aromatic is described. In the pr...
The palladium-promoted deallylation of allylamines derived from primary and secondary amines is achi...
A novel and selective cascade reaction of primary amines and alkynes for the synthesis of the corres...
A series of competition experiments has revealed that selective cleavage of N-benzyl-protected secon...
A number of tertiary N-allyl- and N-propargyl-substituted amines have been prepared by alkylation of...
The first highly effective Pd/C-catalyzed oxidative <i>N</i>-dealkylation/carbonylation of various a...
Propargyloxycarbonyl chloride, 1, has been used to protect the hydroxyl and amino functionalities of...
Propargyloxycarbonyl chloride, 1, has been used to protect the hydroxyl and amino functionalities of...
ZnBr2 in dichloromethane is a convenient reagent for mild and selective removal of the tert-butoxyca...
Treatment of a range of N-benzyl tertiary amines with aqueous eerie ammonium nitrate results in N-de...
N-Alkylation is conceptually the most straightforward disconnection towards secondary and tertiary a...
The invention relates to improved means and methods for N- dealkylation of alkylated amines. Provide...