Mixed M(II)/M(III) metal oxalates, as "stripes" connected through strong hydrogen bonding by para-dimethylaminobenzaldeide (DAMBA) and water, form an organic-inorganic 2D network that enables segregation in layers of the cationic organic NLO-phore trans-4-(4-dimethylaminostyryl)-1-methylpyridinium, [DAMS+]. The crystalline hybrid materials obtained have the general formula [DAMS]4[M2M′(C2O4)6]·2DAMBA·2H2O (M = Rh, Fe, Cr; M′ = Mn, Zn), and their overall three-dimensional packing is non-centrosymmetric and polar, therefore suitable for second harmonic generation (SHG). All the compounds investigated are characterized by an exceptional SHG activity, due both to the large molecular quadratic hyperpolarizability of [DAMS+] and to the efficiency...
New CoII members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O 4)6]...
New CoII members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O 4)6]...
Reaction of 1,2,4-triazole and NaF with M(ox) (M = transition metal dication; ox = oxalate dianio...
Mixed M(II)/M(III) metal oxalates, as "stripes" connected through strong hydrogen bonding by para-di...
Mixed M(II)/M(III) metal oxalates, as "stripes" connected through strong hydrogen bonding by para-di...
Mixed M(II)/M(III) metal oxalates, as "stripes" connected through strong hydrogen bonding by para-di...
Mixed M(II)/M(III) metal oxalates, as "stripes" connected through strong hydrogen bonding by para-di...
Hybrid mixed metal oxalates of general formula [M2IIIMII(C2O4)6] [DAMS]4· 2 DAMBA · 2 H2O, where MII...
Hybrid mixed metal oxalates of general formula [M2IIIMII(C2O4)6] [DAMS]4· 2 DAMBA · 2 H2O, where MII...
Hybrid mixed metal oxalates of general formula [M2IIIMII(C2O4)6] [DAMS]4· 2 DAMBA · 2 H2O, where MII...
Hybrid mixed metal oxalates of general formula [M2IIIMII(C2O4)6] [DAMS]4· 2 DAMBA · 2 H2O, where MII...
New Co-II members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O4)(6...
Hybrid mixed metal oxalates of general formula [M2III MII (C2 O4)6] [DAMS]4 · 2 DAMBA · 2 H2 O, wher...
New CoII members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O 4)6]...
New CoII members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O 4)6]...
New CoII members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O 4)6]...
New CoII members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O 4)6]...
Reaction of 1,2,4-triazole and NaF with M(ox) (M = transition metal dication; ox = oxalate dianio...
Mixed M(II)/M(III) metal oxalates, as "stripes" connected through strong hydrogen bonding by para-di...
Mixed M(II)/M(III) metal oxalates, as "stripes" connected through strong hydrogen bonding by para-di...
Mixed M(II)/M(III) metal oxalates, as "stripes" connected through strong hydrogen bonding by para-di...
Mixed M(II)/M(III) metal oxalates, as "stripes" connected through strong hydrogen bonding by para-di...
Hybrid mixed metal oxalates of general formula [M2IIIMII(C2O4)6] [DAMS]4· 2 DAMBA · 2 H2O, where MII...
Hybrid mixed metal oxalates of general formula [M2IIIMII(C2O4)6] [DAMS]4· 2 DAMBA · 2 H2O, where MII...
Hybrid mixed metal oxalates of general formula [M2IIIMII(C2O4)6] [DAMS]4· 2 DAMBA · 2 H2O, where MII...
Hybrid mixed metal oxalates of general formula [M2IIIMII(C2O4)6] [DAMS]4· 2 DAMBA · 2 H2O, where MII...
New Co-II members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O4)(6...
Hybrid mixed metal oxalates of general formula [M2III MII (C2 O4)6] [DAMS]4 · 2 DAMBA · 2 H2 O, wher...
New CoII members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O 4)6]...
New CoII members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O 4)6]...
New CoII members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O 4)6]...
New CoII members of the family of multifunctional materials of general formula [DAMS]4[M2Co(C2O 4)6]...
Reaction of 1,2,4-triazole and NaF with M(ox) (M = transition metal dication; ox = oxalate dianio...