Greenberger-Horne-Zeilinger (GHZ) states and their mixtures exhibit fascinating properties. A complete basis of GHZ states can be constructed by properly choosing local basis rotations. We demonstrate this experimentally for the Hilbert space C⊗42 by entangling two photons in polarization and orbital angular momentum. Mixing GHZ states unmasks different entanglement features based on their particular local geometrical connectedness. In particular, a specific GHZ state in a complete orthonormal basis has a “twin” GHZ state for which equally mixing leads to full separability in opposition to any other basis-state. Exploiting these local geometrical relations provides a toolbox for generating specific types of multipartite entanglement, each p...