We compute perturbative QCD corrections to B → D form factors at leading power in Λ/m b , at large hadronic recoil, from the light-cone sum rules (LCSR) with B-meson distribution amplitudes in HQET. QCD factorization for the vacuum-to-B-meson correlation function with an interpolating current for the D-meson is demonstrated explicitly at one loop with the power counting scheme mc∼O(Λmb−−−−√). The jet functions encoding information of the hard-collinear dynamics in the above-mentioned correlation function are complicated by the appearance of an additional hard-collinear scale m c , compared to the counterparts entering the factorization formula of the vacuum-to-B-meson correction function for the construction of B → π from factors. Inspectin...