The enantioselective electrophilic fluorination of α-aryl-tetralones is promoted by cinchonine/selectfluor combinations. This strategy allows a facile synthesis of the corresponding 2-fluoro-2-aryl-1-tetralones with excellent yields (up to >98%) and moderate to good enantioselectivity (up to74%).Financial support from Brazilian agencies CAPES, CNPq, FAPERJ and UFRJ is acknowledged. L. G. S. thanks Capes for the fellowship (Process CSF-PVE-S-88887.137162/2017-00). We gratefully acknowledge financial support from the Spanish Ministerio de Economía y Competitividad (MINECO) (projects CTQ2013-43446-P and CTQ2014-51912-REDC) the Spanish Ministerio de Economía, Industria y Competitividad, Agencia Estatal de Investigación (AEI) and Fondo Europeo d...
The enantioselective synthesis of fluorinated molecules has drawn much attention within the chemical...
This thesis has focussed on three main projects, all concerning electrophilic fluorination and fluor...
A general method for the enantioselective synthesis of carbo- and heterocyclic carbonyl compounds be...
International audienceFrom 2000, our two research groups independently and simultaneously designed a...
The introduction of fluorine into molecules is an important tool in the agrochemical and pharmaceuti...
Enantioenriched fluorinated heterocycles can be prepared through fluorocyclizations of prochiral ind...
The chemistry of bioactive organofluorine compounds is a rapidly developing area of research because...
We report a catalytic enantioselective electrophilic fluorination of alkenes to form tertiary and qu...
The combination of a practical and highly enantioselective organocatalytic reaction, which allows th...
In this thesis, the synthesis, reactivity and enantioselectivity of novel chiral Selectfluor Analogu...
The enantioselective synthesis of tetralin derivatives bearing a trifluoromethylated all‐carbon quat...
Conspectus The vicinal fluorofunctionalization of alkenes is an attractive transformation that conve...
Enantiopure N-fluorocinchona alkaloids promoted the electrophilic fluorodesilylation of allyl silane...
Fluorine is the most electronegative element in the periodic table, and the introduction of one or m...
A newly designed thiazoline iminopyridine ligand for enantioselective cobalt-catalyzed sequential Na...
The enantioselective synthesis of fluorinated molecules has drawn much attention within the chemical...
This thesis has focussed on three main projects, all concerning electrophilic fluorination and fluor...
A general method for the enantioselective synthesis of carbo- and heterocyclic carbonyl compounds be...
International audienceFrom 2000, our two research groups independently and simultaneously designed a...
The introduction of fluorine into molecules is an important tool in the agrochemical and pharmaceuti...
Enantioenriched fluorinated heterocycles can be prepared through fluorocyclizations of prochiral ind...
The chemistry of bioactive organofluorine compounds is a rapidly developing area of research because...
We report a catalytic enantioselective electrophilic fluorination of alkenes to form tertiary and qu...
The combination of a practical and highly enantioselective organocatalytic reaction, which allows th...
In this thesis, the synthesis, reactivity and enantioselectivity of novel chiral Selectfluor Analogu...
The enantioselective synthesis of tetralin derivatives bearing a trifluoromethylated all‐carbon quat...
Conspectus The vicinal fluorofunctionalization of alkenes is an attractive transformation that conve...
Enantiopure N-fluorocinchona alkaloids promoted the electrophilic fluorodesilylation of allyl silane...
Fluorine is the most electronegative element in the periodic table, and the introduction of one or m...
A newly designed thiazoline iminopyridine ligand for enantioselective cobalt-catalyzed sequential Na...
The enantioselective synthesis of fluorinated molecules has drawn much attention within the chemical...
This thesis has focussed on three main projects, all concerning electrophilic fluorination and fluor...
A general method for the enantioselective synthesis of carbo- and heterocyclic carbonyl compounds be...