C.J. and A.S. thank the Australian Research Council for financial support. C.J. also thanks the U.S. Air Force Asian Office of Aerospace Research and Development (grant FA2386-14-1-4043).The first examples of magnesium acyls, [(Nacnac)Mg{μ-C(Ph)O}(μ-OR)Mg(Nacnac)] (R = Me, But or Ph; Nacnac = [HC(MeCNAr)2]-; Ar = C6H2Me3-2,4,6 (MesNacnac), C6H3Et2-2,6 (DepNacnac), C6H3Pri2-2,6 (DipNacnac)), have been prepared by reductive cleavage of a series of esters using dimeric magnesium(I) reducing agents, [{(Nacnac)Mg}2]. Crystallographic studies reveal the complexes to be dimeric, being bridged by both phenyl-acyl and alkoxide/aryloxide fragments. The crystal structures, combined with results of spectroscopic and computational studies suggest that t...
An extremely bulky, symmetrical three-coordinate magnesium(i) complex, [{(TCHPNacnac)Mg}2] (TCHPNacn...
The synthesis of chelating N-heterocyclic carbene (NHC) complexes with considerable π-acceptor prope...
The cationic magnesium moiety of magnesium organohalo aluminate complexes, relevant to rechargeable ...
The first examples of magnesium acyls, [(Nacnac)Mg{μ-C(Ph)O}(μ-OR)Mg(Nacnac)] (R=Me, tBu or Ph; Nacn...
bibtex: ISI:000412595600030 bibtex\location:'POSTFACH 101161, 69451 WEINHEIM, GERMANY',publisher:'WI...
Financial support from the Australian Research Council (CJ), the U.S. Air Force Asian Office of Aero...
The authors thank the Australian Research Council (C.J.), The U.S. Air Force Asian Office of Aerospa...
Cationic alkaline-earth complexes attract interest for their enhanced Lewis acidity and reactivity c...
The oxidative insertion of 1,1-diphenylethylene into the Mg-Mg bond of two magnesium(I) dimers, [(Ar...
The insertion of 1,1-diphenylethylene into the Mg–Mg bond of two magnesium(I) dimers, [(<sup>Ar</su...
Reactions of three magnesium(i) dimers, [{( Ar Nacnac)Mg-} 2 ] ( Ar Nacnac = [(ArNCMe) 2 CH] − ; Ar ...
We thank the University of St Andrews and the EPSRC doctoral training grant (EP/N509759/1) for suppo...
bibtex: ISI:000418783600015 bibtex\location:'1155 16TH ST, NW, WASHINGTON, DC 20036 USA',publisher:'...
This study details syntheses of unsymmetrical magnesium(I)–adduct complexes, [(ArNacnac)(D)Mg–Mg...
The synthesis, characterisation and reactivity of two isostructural anionic magnesium and calcium co...
An extremely bulky, symmetrical three-coordinate magnesium(i) complex, [{(TCHPNacnac)Mg}2] (TCHPNacn...
The synthesis of chelating N-heterocyclic carbene (NHC) complexes with considerable π-acceptor prope...
The cationic magnesium moiety of magnesium organohalo aluminate complexes, relevant to rechargeable ...
The first examples of magnesium acyls, [(Nacnac)Mg{μ-C(Ph)O}(μ-OR)Mg(Nacnac)] (R=Me, tBu or Ph; Nacn...
bibtex: ISI:000412595600030 bibtex\location:'POSTFACH 101161, 69451 WEINHEIM, GERMANY',publisher:'WI...
Financial support from the Australian Research Council (CJ), the U.S. Air Force Asian Office of Aero...
The authors thank the Australian Research Council (C.J.), The U.S. Air Force Asian Office of Aerospa...
Cationic alkaline-earth complexes attract interest for their enhanced Lewis acidity and reactivity c...
The oxidative insertion of 1,1-diphenylethylene into the Mg-Mg bond of two magnesium(I) dimers, [(Ar...
The insertion of 1,1-diphenylethylene into the Mg–Mg bond of two magnesium(I) dimers, [(<sup>Ar</su...
Reactions of three magnesium(i) dimers, [{( Ar Nacnac)Mg-} 2 ] ( Ar Nacnac = [(ArNCMe) 2 CH] − ; Ar ...
We thank the University of St Andrews and the EPSRC doctoral training grant (EP/N509759/1) for suppo...
bibtex: ISI:000418783600015 bibtex\location:'1155 16TH ST, NW, WASHINGTON, DC 20036 USA',publisher:'...
This study details syntheses of unsymmetrical magnesium(I)–adduct complexes, [(ArNacnac)(D)Mg–Mg...
The synthesis, characterisation and reactivity of two isostructural anionic magnesium and calcium co...
An extremely bulky, symmetrical three-coordinate magnesium(i) complex, [{(TCHPNacnac)Mg}2] (TCHPNacn...
The synthesis of chelating N-heterocyclic carbene (NHC) complexes with considerable π-acceptor prope...
The cationic magnesium moiety of magnesium organohalo aluminate complexes, relevant to rechargeable ...