Solvent polarity has been known to influence the triplet state structure and reactivity. Here, we present our experimental and theoretical study on the effect of solvent on the lowest triplet excited state structure of 2-chlorothioxanthone (CTX). Time-resolved absorption (TA) spectroscopy has been employed to understand the triplet state electronic structure; whereas solvent-induced structural changes have been studied using time-resolved resonance Raman (TR3) spectroscopy. Both the DFT and TD-DFT calculations have been performed in the solution phase employing self-consistent reaction field implicit solvation model to support the experimental data. It has been observed that CO stretching frequencies of the excited triplet state are sensiti...
The structure, dynamics, and hydrogen bonding effects on the triplet state of the phototrigger model...
Time-resolved resonance Raman spectroscopy (TR3) has been used to study the effect of solvent polari...
Time-resolved resonance Raman spectroscopy (TR3) has been used to study the effect of solvent pola...
Substitution plays an important role in determining the triplet state reactivity. In this paper, we ...
Solvents are known to affect the triplet state structure and reactivity. In this paper, we have empl...
Solvent effects, especially intermolecular hydrogen bonding, play a central role in the photophysics...
Thioxanthone has been investigated extensively owing to its unique photochemical and photophysical a...
The effect of solvent on chemical reactivity has generally been explained on the basis of the dielec...
In solution, the environment around the solute is determined solely by the solvent molecules, which ...
Thioxanthone (TX), an aromatic ketone, exhibits significant solvent-dependent photophysical properti...
Thioxanthone (TX), an aromatic ketone, exhibits significant solvent-dependent photophysical properti...
The solvent plays a decisive role in the photochemistry and photophysics of aromatic ketones. Xantho...
The photochemistry of aromatic ketones plays a key role in various physicochemical and biological pr...
In this work we analyzed the infrared and visible transient absorption spectra of all-trans-β-apo-8'...
Solvent effects play a vital role in various chemical, physical, and biological processes. To gain a...
The structure, dynamics, and hydrogen bonding effects on the triplet state of the phototrigger model...
Time-resolved resonance Raman spectroscopy (TR3) has been used to study the effect of solvent polari...
Time-resolved resonance Raman spectroscopy (TR3) has been used to study the effect of solvent pola...
Substitution plays an important role in determining the triplet state reactivity. In this paper, we ...
Solvents are known to affect the triplet state structure and reactivity. In this paper, we have empl...
Solvent effects, especially intermolecular hydrogen bonding, play a central role in the photophysics...
Thioxanthone has been investigated extensively owing to its unique photochemical and photophysical a...
The effect of solvent on chemical reactivity has generally been explained on the basis of the dielec...
In solution, the environment around the solute is determined solely by the solvent molecules, which ...
Thioxanthone (TX), an aromatic ketone, exhibits significant solvent-dependent photophysical properti...
Thioxanthone (TX), an aromatic ketone, exhibits significant solvent-dependent photophysical properti...
The solvent plays a decisive role in the photochemistry and photophysics of aromatic ketones. Xantho...
The photochemistry of aromatic ketones plays a key role in various physicochemical and biological pr...
In this work we analyzed the infrared and visible transient absorption spectra of all-trans-β-apo-8'...
Solvent effects play a vital role in various chemical, physical, and biological processes. To gain a...
The structure, dynamics, and hydrogen bonding effects on the triplet state of the phototrigger model...
Time-resolved resonance Raman spectroscopy (TR3) has been used to study the effect of solvent polari...
Time-resolved resonance Raman spectroscopy (TR3) has been used to study the effect of solvent pola...