A perturbation treatment was developed for the comparative study of the abstraction of hydrogen from methane by formaldehyde and thioformaldehyde in their nπ* and ππ* states. Both in-plane and perpendicularplane reactions are considered. Results are qualitative but reveal clearly the prominent distinguishing features of these two photochemical processes in agreement with the experimental observations
International audienceTwo mechanisms of hydrogen transfer are often observed in photochemical reacti...
The energy profiles for radical dissociation of the lowest triplet state of various symmetric and no...
UV irradiation of 1,2,3-indanetrione, in CH2Cl2, in the presence of 2,3-dimethyl-2-butene yields a c...
A perturbation treatment was developed for the comparative study of the abstraction of hydrogen from...
The change in energy during hydrogen abstraction by ketones is estimated for different electronic st...
Photoinduced hydrogen abstraction reaction, which is bett-er known as the Norrish type II reaction, ...
Qualitative potential energy surfaces for hydrogen abstraction from alkanes containing primary, seco...
Author Institution: Chemistry Department, University of Wisconsin - Madison, Madison, Wisconsin 5370...
Intramolecular gamma-hydrogen abstraction reactions were examined in pentane-2-one and 2-methyl-1-pe...
Photochemical cyclization of carbonyl compounds to give cyclopropanols via β-hydrogen transfer to ca...
The intramolecular abstraction of a f-hydrogen by photoexcited aryl alkyl ketones has excited recent...
The influence of hydrogen bonding in affecting the photochemistry and reactivity of several molecula...
Ketene was flash photolysed at wavelengths greater than 160 nm. The photolysis lamp was of a four el...
International audienceH-addition reactions on the icy interstellar grains may play an important role...
Graduation date: 1987The relative rates of hydrogen atom abstraction from a series of\ud 13 homoaryl...
International audienceTwo mechanisms of hydrogen transfer are often observed in photochemical reacti...
The energy profiles for radical dissociation of the lowest triplet state of various symmetric and no...
UV irradiation of 1,2,3-indanetrione, in CH2Cl2, in the presence of 2,3-dimethyl-2-butene yields a c...
A perturbation treatment was developed for the comparative study of the abstraction of hydrogen from...
The change in energy during hydrogen abstraction by ketones is estimated for different electronic st...
Photoinduced hydrogen abstraction reaction, which is bett-er known as the Norrish type II reaction, ...
Qualitative potential energy surfaces for hydrogen abstraction from alkanes containing primary, seco...
Author Institution: Chemistry Department, University of Wisconsin - Madison, Madison, Wisconsin 5370...
Intramolecular gamma-hydrogen abstraction reactions were examined in pentane-2-one and 2-methyl-1-pe...
Photochemical cyclization of carbonyl compounds to give cyclopropanols via β-hydrogen transfer to ca...
The intramolecular abstraction of a f-hydrogen by photoexcited aryl alkyl ketones has excited recent...
The influence of hydrogen bonding in affecting the photochemistry and reactivity of several molecula...
Ketene was flash photolysed at wavelengths greater than 160 nm. The photolysis lamp was of a four el...
International audienceH-addition reactions on the icy interstellar grains may play an important role...
Graduation date: 1987The relative rates of hydrogen atom abstraction from a series of\ud 13 homoaryl...
International audienceTwo mechanisms of hydrogen transfer are often observed in photochemical reacti...
The energy profiles for radical dissociation of the lowest triplet state of various symmetric and no...
UV irradiation of 1,2,3-indanetrione, in CH2Cl2, in the presence of 2,3-dimethyl-2-butene yields a c...