Copper(II) complexes of tridentate SNO ligands: synthesis, characterization and crystal structure

A new series of binary copper(II) complexes, [Cu(L)2] (2) [where L is a monobasic tridentate methylthioazophenolate having NSO donor sets], has been synthesized. The reddish brown colored complexes have been characterized by elemental analyses, spectroscopic and other physico-chemical tools. The detailed structure analysis of one of the complexes, [Cu(1a)2] (2a), by single-crystal X-ray crystallography shows that thioether-S donor center participates in coordination with the copper(II) ion with a weak interaction with long Cu-S(thioether) bond distances [2.956(2) and 2.925(2) ]. Electrochemical study of the complexes in methanol using TBAP as supporting electrolyte shows that heterogeneous electron-transfer rate is low at the applied potential