An enantiospecific synthesis of a thapsane containing an oxygen substituent at the C-3 position is accomplished starting from (R)-carvone. A Claisen rearrangement and an intramolecular diazoketone cyclopropanation reaction were employed for the stereo- and regiospecific generation of the three contiguous quaternary carbon atoms present in the thapsanes
Synthesis of (±)-3-methoxythapsene via stereospecific construction of three contiguous quaternary ca...
Stereo- and enantiospecific synthesis of (+)-valerane starting from R-carvone utilising orthoester C...
The synthesis of (±)-3a,4,4,7a-tetramethylhydrindan-2-one 8, containing three contiguous quaternary ...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
449-459Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small g...
Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small group of...
First enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxythapsan-...
413-422First enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxytha...
The first enantiospecific synthesis of (+)-cis,anti,cis-1,8,12,12-tetramethyl-4-oxatricyclo[6.4.0.02...
The enantiospecific first total synthesis of 10-hydroxy-10,11-epoxythapsan-5-yl senecioate (+)-1f, t...
1029-1039Enantiospecific synthesis of 3-thapsenol, comprising the carbon framework of a small group...
Enantiospecific total synthesis of optical antipode of the sesquiterpene 5-senecioyloxy-10,11-epoxyt...
An enantiospecific approach to a functionalised carbon framework of the sesquiterpenes, cyperanes, s...
Synthesis of (±)-3-methoxythapsene via stereospecific construction of three contiguous quaternary ca...
Stereo- and enantiospecific synthesis of (+)-valerane starting from R-carvone utilising orthoester C...
The synthesis of (±)-3a,4,4,7a-tetramethylhydrindan-2-one 8, containing three contiguous quaternary ...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
The first enantiospecific synthesis of a thapsane, containing three contiguous quaternary carbon ato...
449-459Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small g...
Enantiospecific synthesis of thaps-8-en-5-ol, comprising of the carbon framework of a small group of...
First enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxythapsan-...
413-422First enantiospecific total synthesis of optical antipode of the sesquiterpene 10,11-epoxytha...
The first enantiospecific synthesis of (+)-cis,anti,cis-1,8,12,12-tetramethyl-4-oxatricyclo[6.4.0.02...
The enantiospecific first total synthesis of 10-hydroxy-10,11-epoxythapsan-5-yl senecioate (+)-1f, t...
1029-1039Enantiospecific synthesis of 3-thapsenol, comprising the carbon framework of a small group...
Enantiospecific total synthesis of optical antipode of the sesquiterpene 5-senecioyloxy-10,11-epoxyt...
An enantiospecific approach to a functionalised carbon framework of the sesquiterpenes, cyperanes, s...
Synthesis of (±)-3-methoxythapsene via stereospecific construction of three contiguous quaternary ca...
Stereo- and enantiospecific synthesis of (+)-valerane starting from R-carvone utilising orthoester C...
The synthesis of (±)-3a,4,4,7a-tetramethylhydrindan-2-one 8, containing three contiguous quaternary ...