Add to ORKGA total synthesis of cucumin E, a recently isolated triquinane natural product with a new carbon framework, has been achieved. The key step is the flash vacuum pyrolysis (FVP)-induced cyclobutane fragmentation in a readily available pentacyclic caged dione to deliver the triquinane skeleton with functionalization in all the three five-membered rings suitable for further elaboration to the natural product
Pentalenic acid, 5, and pentalenene, 4, and their C-9 epimers 5a and 4a, respectively, were synthesi...
The first total synthesis of the biogenetically important and structurally novel triquinane sesquit...
The enantiomerically pure cis-1,2-dihydrocatechol 6, which is readily obtained via the whole-cell bi...
A total synthesis of cucumin E, a recently isolated triquinane natural product with a new carbon fra...
1092-1106Enantiospecific first total synthesis of the linear triquinane sesquiterpene cucumin-H has...
The first total synthesis of the sesquiterpene (-)-cucumin H, a linear triquinane isolated from Macr...
1556-1563Diverse cis-syn-cis and cis-anti-cis triquinane frameworks have been assembled by a simple ...
Diverse cis-syn-cis and cis-anti-cis triquinane frameworks have been assembled by a simple synthetic...
Fifteen examples of a new, speedy and general approach to linearly fused tricyclopentanoids bearing ...
A total synthesis of the recently reported triquinane natural product dichomitol, isolated from the ...
The first total synthesis of the triquinane based sesquiterpenoid antibiotics (±)-pleurotellol and (...
Triquinanes and their oxygenated congeners, oxa- and dioxa-triquinanes, exhibit versatile biological...
A total synthesis of the 'putative structure' 7, attributed to the novel triquinane sesquiterpene is...
Enantiospecific first total synthesis of the angular triquinane sesquiterpene (65,7R)-silphiperfolan...
A very versatile diquinane intermediate, ($\pm$)-8$\alpha$-hydroxy-3,7,7-trimethyl-4-isobutoxy-$1\al...
Pentalenic acid, 5, and pentalenene, 4, and their C-9 epimers 5a and 4a, respectively, were synthesi...
The first total synthesis of the biogenetically important and structurally novel triquinane sesquit...
The enantiomerically pure cis-1,2-dihydrocatechol 6, which is readily obtained via the whole-cell bi...
A total synthesis of cucumin E, a recently isolated triquinane natural product with a new carbon fra...
1092-1106Enantiospecific first total synthesis of the linear triquinane sesquiterpene cucumin-H has...
The first total synthesis of the sesquiterpene (-)-cucumin H, a linear triquinane isolated from Macr...
1556-1563Diverse cis-syn-cis and cis-anti-cis triquinane frameworks have been assembled by a simple ...
Diverse cis-syn-cis and cis-anti-cis triquinane frameworks have been assembled by a simple synthetic...
Fifteen examples of a new, speedy and general approach to linearly fused tricyclopentanoids bearing ...
A total synthesis of the recently reported triquinane natural product dichomitol, isolated from the ...
The first total synthesis of the triquinane based sesquiterpenoid antibiotics (±)-pleurotellol and (...
Triquinanes and their oxygenated congeners, oxa- and dioxa-triquinanes, exhibit versatile biological...
A total synthesis of the 'putative structure' 7, attributed to the novel triquinane sesquiterpene is...
Enantiospecific first total synthesis of the angular triquinane sesquiterpene (65,7R)-silphiperfolan...
A very versatile diquinane intermediate, ($\pm$)-8$\alpha$-hydroxy-3,7,7-trimethyl-4-isobutoxy-$1\al...
Pentalenic acid, 5, and pentalenene, 4, and their C-9 epimers 5a and 4a, respectively, were synthesi...
The first total synthesis of the biogenetically important and structurally novel triquinane sesquit...
The enantiomerically pure cis-1,2-dihydrocatechol 6, which is readily obtained via the whole-cell bi...