Simple and preparatively efficacious lipase-catalysed kinetic resolution of endo,endo–cis-bicyclo[3.3.0]octane-2,6-diol rac-3 has provided ready access to bicyclo[3.3.0]octane-2,6-diones (−)-2 and (+)-2 of high enantiomeric purity. These C2-symmetric diones have been further elaborated to the sesquiterpene hydrocarbon (+)-kelsoene 1 and ent-kelsoene (−)-1, respectively, thereby establishing the absolute configuration of the natural product. In the light of these results, the absolute configuration assigned earlier to (+)-kelsoene needs to be revised as (+)-1
An enantioselective total synthesis of two sesquiterpenoids, kopeolin and kopeolone, has been achiev...
Stereoselective 9-step conversions of the ketone 17 into the tricyclic ketone 31 via two similar syn...
International audienceAn enantioselective total synthesis of two sesquiterpenoids, kopeolin and kope...
Simple and preparatively efficacious lipase-catalysed kinetic resolution of endo,endo–cis-bicyclo[3....
Simple and preparatively efficacious lipase-catalysed kinetic resolution of endo,endo-cis-bicyclo[3....
Formal total syntheses of the natural enantiomeric forms of the title sesquiterpenes 1 and 2 have be...
The enantiomerically pure cis-1,2-dihydrocatechols 2, which are generated by enzymatic dihydroxylati...
An enantioselective total synthesis of (−)-sulcatine G 4 from the readily available (+)-diquinane d...
Employing commercially available 1,5-cyclooctadiene 5 as the starting material, the first total synt...
Employing commercially available 1,5-cyclooctadiene 5 as the starting material, the first total synt...
The total synthesis of the unique tricyclic terpene natural product (±)-kelsoene was achieved in 15 ...
An enantiomerically pure cis-1,2-dihydrocatechol, which is readily obtained via a toluene dioxygenas...
Total syntheses of title natural products, 1 and 2, have been achieved using the cis-1,2-dihydrocate...
This thesis describes the synthesis of a series of enantiomerically pure cis-fused bicyclic trimethy...
The first total synthesis of the hirsutene-type sesquiterpenoid natural product (+)-connatusin B (2)...
An enantioselective total synthesis of two sesquiterpenoids, kopeolin and kopeolone, has been achiev...
Stereoselective 9-step conversions of the ketone 17 into the tricyclic ketone 31 via two similar syn...
International audienceAn enantioselective total synthesis of two sesquiterpenoids, kopeolin and kope...
Simple and preparatively efficacious lipase-catalysed kinetic resolution of endo,endo–cis-bicyclo[3....
Simple and preparatively efficacious lipase-catalysed kinetic resolution of endo,endo-cis-bicyclo[3....
Formal total syntheses of the natural enantiomeric forms of the title sesquiterpenes 1 and 2 have be...
The enantiomerically pure cis-1,2-dihydrocatechols 2, which are generated by enzymatic dihydroxylati...
An enantioselective total synthesis of (−)-sulcatine G 4 from the readily available (+)-diquinane d...
Employing commercially available 1,5-cyclooctadiene 5 as the starting material, the first total synt...
Employing commercially available 1,5-cyclooctadiene 5 as the starting material, the first total synt...
The total synthesis of the unique tricyclic terpene natural product (±)-kelsoene was achieved in 15 ...
An enantiomerically pure cis-1,2-dihydrocatechol, which is readily obtained via a toluene dioxygenas...
Total syntheses of title natural products, 1 and 2, have been achieved using the cis-1,2-dihydrocate...
This thesis describes the synthesis of a series of enantiomerically pure cis-fused bicyclic trimethy...
The first total synthesis of the hirsutene-type sesquiterpenoid natural product (+)-connatusin B (2)...
An enantioselective total synthesis of two sesquiterpenoids, kopeolin and kopeolone, has been achiev...
Stereoselective 9-step conversions of the ketone 17 into the tricyclic ketone 31 via two similar syn...
International audienceAn enantioselective total synthesis of two sesquiterpenoids, kopeolin and kope...
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