Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents
- Hoffmann, Herbert C.
- Paasch, Silvia
- Müller, Philipp
- Senkovska, Irena
- Padmanaban, Mohan
- Glorius, Frank
- Kaskel, Stefan
- Brunner, Eike
DOIAbstract
Recently, we have described the synthesis of chiral metal–organic frameworks iPr-ChirUMCM-1 and Bn-ChirUMCM-1 and their use in enantioselective separation. Here, we demonstrate for the first time the use of a chiral solvating agent (1-phenyl-2,2,2-trifluoroethanol, TFPE) for chiral recognition in iPr-ChirUMCM-1 and Bn-ChirUMCM-1 by means of solid-state13C NMR spectroscopy.Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich
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