Retrieving the ion mobility ratio and aerosol charge fractions for a neutralizer in real-world applications

<p>Electrical mobility size spectrometers (with a neutralizer, an electrical mobility classifier, and a detector as key components) are widely used to measure aerosol size distributions. The performance of a neutralizer is often evaluated separately from the spectrometer. In real-world applications of a neutralizer, i.e., typically with uncontrolled composition of the neutralizer carrier gas including trace constituents that can lead to variabilities in properties of positive and negative ions, charge fractions may differ from those predicted by widely used aerosol charging models with fixed ion properties and subsequently cause significant uncertainties in reported aerosol size distributions. In this study, we proposed an empirical method to retrieve the variations in neutralizer ion properties and aerosol charge fractions when measuring aerosol size distributions. Our approach requires measuring both positively and negatively charged particles using the electrical mobility size spectrometer to provide information on the performance of the neutralizer. Bipolar diffusion charging theories were applied to illustrate that aerosol charge fractions are governed by the mobility ratio of positive and negative ions. Positively and negatively charged particles measured by the spectrometer can be used to estimate the mobility ratio of positive and negative ions for the neutralizer. A modified Gunn and Woessner’s formula can then be used to calculate aerosol charge fractions from the retrieved ion mobility ratio. These charge fractions can be used for size distribution data inversion. Both simulated aerosols and experiments were used to evaluate the proposed method. We found that this new method can capture the variations in neutralizer ion properties and aerosol charge fractions under various conditions and help to achieve more accurate measurement of aerosol size distributions.</p> <p>Copyright © 2018 American Association for Aerosol Research