A New Porous Three-Dimensional Iron(II) Coordination Polymer with Solvent-Induced Reversible Spin-Crossover Behavior
- Yan Meng (28903)
- Yan-Jie Dong (5575505)
- Zheng Yan (194231)
- Yan-Cong Chen (1411087)
- Xiao-Wei Song (343785)
- Quan-Wen Li (1755667)
- Chuan-Lei Zhang (810821)
- Zhao-Ping Ni (1637287)
- Ming-Liang Tong (1411093)
Publication date
July 2018
DOIAbstract
A new Hofmann-type porous coordination polymer [Fe(dpni){Ag(CN)<sub>2</sub>}<sub>2</sub>]·4CH<sub>3</sub>CN (dpni = <i>N</i>,<i>N</i>′-di-(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide) with the topology of pcu net has been synthesized. It exhibits two-step spin-crossover behavior. Moreover, reversible changes between incomplete and two-step spin-crossover properties were associated with the desorption/resorption of the CH<sub>3</sub>CN solvent molecules
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