Using Morita–Baylis–Hillman Acetates of 2-Azidobenzaldehydes for the Synthesis of 2-Alkoxy-3-Cyanomethylquinolines and Alkyl Quinoline-3-Carboxylates

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Publication date

July 2011

DOI

10.1002/jhet.667

Publisher

HETERO CORPORATION

Abstract

A simple method for the synthesis of several 2?alkoxy?3?cyanomethylquinolines and alkyl quinoline?3?carboxylates using iminophosphorane?mediated cyclization reactions of 3?(2?azidophenyl)?2?cyanomethylpropenoates and 3?(2?azidophenyl)?2 nitromethylpropenoates has been developed. These compounds were readily obtained from the Morita?Baylis?Hillman acetates of 2?azidobenzaldehydes using potassium cyanide or sodium nitrite, respectively. J. Heterocyclic Chem., (2011

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Using Morita–Baylis–Hillman Acetates of 2-Azidobenzaldehydes for the Synthesis of 2-Alkoxy-3-Cyanomethylquinolines and Alkyl Quinoline-3-Carboxylates

Abstract

Extracted data

Using Morita–Baylis–Hillman Acetates of 2-Azidobenzaldehydes for the Synthesis of 2-Alkoxy-3-Cyanomethylquinolines and Alkyl Quinoline-3-Carboxylates

Abstract

Extracted data

Related items

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Using Morita&ndash;Baylis&ndash;Hillman Acetates of 2-Azidobenzaldehydes for the Synthesis of 2-Alkoxy-3-Cyanomethylquinolines and Alkyl Quinoline-3-Carboxylates

Abstract

Extracted data

Using Morita&ndash;Baylis&ndash;Hillman Acetates of 2-Azidobenzaldehydes for the Synthesis of 2-Alkoxy-3-Cyanomethylquinolines and Alkyl Quinoline-3-Carboxylates

Abstract

Extracted data

Related items

Related items

Using Morita–Baylis–Hillman Acetates of 2-Azidobenzaldehydes for the Synthesis of 2-Alkoxy-3-Cyanomethylquinolines and Alkyl Quinoline-3-Carboxylates

Using Morita–Baylis–Hillman Acetates of 2-Azidobenzaldehydes for the Synthesis of 2-Alkoxy-3-Cyanomethylquinolines and Alkyl Quinoline-3-Carboxylates