Jutzi P, WIELAND W, NEUMANN B, Stammler H-G. SLIPPED SANDWICH STRUCTURES IN THE CHEMISTRY OF CYCLOPENTADIENYL COPPER-COMPOUNDS. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 1995;501(1-2):369-374.Copper is the only element in the 3d series from which no dicyclopentadienyl compounds are known to date. Starting from cyclopentadienyllithium and copper(I) chloride, two novel organocuprates, [PPh(4)][CuCp(2)] (1) and [Li(12-crown-4)(2)][Cu(2)Cp(3)]. 2THF (2), were prepared. The solid-state structural features in the anions of 1 and 2 are hitherto unknown; eta(2)-Cp coordination to the copper centres is observed by X-ray analysis. NMR spectroscopic analyses confirm the pronounced molecular dynamics in solution. Compounds of the general-formula LiCu(C(5)R(...
The sandwich lutetacyclopentadiene <b>2</b> can be obtained in high yield by the 1:1 reaction of the...
CHEN H, Jutzi P, LEFFERS W, OLMSTEAD MM, POWER PP. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE ...
Summary. The technique of X-ray diffraction has been used to investigate compounds which show charge...
The sandwich lutetacyclopentadiene 2 can be obtained in high yield by the 1:1 reaction of the 1,4-di...
Copper-catalyzed and organocopper-involved reactions are of great significance in organic synthesis....
Two complexes containing copper(I) chloride and (-)-sparteine (spa), namely [Cu(2)Cl(2)spa(2)] and [...
Carbon tetrachloride (CCl4) is a potential environmental contaminant in water, and soil. We are inte...
Carbon Tertrachloride (CT) is a potential environmental contaminants in water, and soil. We are inte...
Copper(l) complexes of 1,2-bis(diphenylphosphino)ethane (dppe) with a stoichiometry Cu-2(dppe)(3)(X)...
The title compound, [Cu(C(10)H(9)N(2)O)(2)] or [Cu(II)(CYMB)(2)], (I), was obtained in an attempt to...
The thermally stable arylmetal-IB-lithium compounds (2-Me{2}NCHZC{6}H{4}){4}M{2}Li{2} (M = Cu, Ag or...
A new cyclic octapeptide, cyclo(Ile-Ser-(Gly)Thz-Ile-Thr-(Gly)Thz) (PatN), related to patellamide A,...
Jutzi P. Sandwich-type cyclopentadienyl complexes of main-group elements. CHEMIE IN UNSERER ZEIT. 19...
[Cu-C6F5]4 is a thermally stable and soluble compound with suitable reactivity for synthetic applica...
The first reports on copper-mediated organic reactions and speculations about the role of presumed o...
The sandwich lutetacyclopentadiene <b>2</b> can be obtained in high yield by the 1:1 reaction of the...
CHEN H, Jutzi P, LEFFERS W, OLMSTEAD MM, POWER PP. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE ...
Summary. The technique of X-ray diffraction has been used to investigate compounds which show charge...
The sandwich lutetacyclopentadiene 2 can be obtained in high yield by the 1:1 reaction of the 1,4-di...
Copper-catalyzed and organocopper-involved reactions are of great significance in organic synthesis....
Two complexes containing copper(I) chloride and (-)-sparteine (spa), namely [Cu(2)Cl(2)spa(2)] and [...
Carbon tetrachloride (CCl4) is a potential environmental contaminant in water, and soil. We are inte...
Carbon Tertrachloride (CT) is a potential environmental contaminants in water, and soil. We are inte...
Copper(l) complexes of 1,2-bis(diphenylphosphino)ethane (dppe) with a stoichiometry Cu-2(dppe)(3)(X)...
The title compound, [Cu(C(10)H(9)N(2)O)(2)] or [Cu(II)(CYMB)(2)], (I), was obtained in an attempt to...
The thermally stable arylmetal-IB-lithium compounds (2-Me{2}NCHZC{6}H{4}){4}M{2}Li{2} (M = Cu, Ag or...
A new cyclic octapeptide, cyclo(Ile-Ser-(Gly)Thz-Ile-Thr-(Gly)Thz) (PatN), related to patellamide A,...
Jutzi P. Sandwich-type cyclopentadienyl complexes of main-group elements. CHEMIE IN UNSERER ZEIT. 19...
[Cu-C6F5]4 is a thermally stable and soluble compound with suitable reactivity for synthetic applica...
The first reports on copper-mediated organic reactions and speculations about the role of presumed o...
The sandwich lutetacyclopentadiene <b>2</b> can be obtained in high yield by the 1:1 reaction of the...
CHEN H, Jutzi P, LEFFERS W, OLMSTEAD MM, POWER PP. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE ...
Summary. The technique of X-ray diffraction has been used to investigate compounds which show charge...