Metal-oxide based nanoobjects: Reactivity, building blocks for polymeric structures and structural variety

Müller A, Roy S. Metal-oxide based nanoobjects: Reactivity, building blocks for polymeric structures and structural variety. USPEKHI KHIMII. 2002;71(12):1107-1119.From the unique library of molybdenum-oxide based building blocks/fragments under reducing conditions in aqueous solution a huge variety of nanoobjects, allowing specific reactions at well-defined positions, can be generated. This enables us to perform a new type of nanochemistry. Examples include the well-known molecular big-wheel of the type {Mo-176} and big-ball of the type {Mo-132} including their derivatives which are considered here. In addition, the by far largest structurally well-characterised cluster having 368 molybdenum atoms with the shape of a lemon is outlined and discussed