Methanol synthesis from CO2/H2 using Ga2O3-Pd/SiO2 catalysts: Impact of reaction products
- Chiavassa, Dante Luis
- Barrandeguy, Julieta
- Bonivardi, Adrian Lionel
- Baltanas, Miguel Angel
DOIAbstract
The synthesis of CH3OH from CO2/H2 mixtures using Ga2O3–Pd/SiO2 promoted catalysts is strongly affected by the reaction products. At finite conversion, important amounts of water and carbon monoxide are also found in the system and, therefore, a comprehensive evaluation of their impact on the process is particularly relevant. An experimental program was conducted, using a plug-flow, differential reactor and a Berty-type CSTR recycle reactor, for a wide range of temperature (508–538 K), pressure (1–4 MPa), composition (H2/CO2 = 1, 3 and 6) and space velocity, including H2–CO–CO2 and H2–He–CO2 ternary mixtures as well. The deleterious effect of CO is attributed to its strong chemisorptive bonding onto the metal, which hampers the generation a...
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