Structure transitions between copper UPD adlayers on Au(111)-(1 × 1) in sulfuric acid and chloride containing electrolyte were investigated by in situ scanning tunnelling microscopy. We demonstrate that co-adsorbed sulphate ions in the (√3 × √3)R30° UPD adlayer are replaced by chloride ions and, depending on the halide coverage, a commensurate (2 × 2) or a slightly distorted (5 × 5)-like Cu-Cl UPD adlayer are formed. The stability ranges of these phases are controlled both by the electrode potential and the Cl− concentration. Phase transitions between the three UPD phases were monitored by time-resolved in situ STM. The observed structure details were attributed to mechanisms based on two-dimensional nucleation and growth processe
Underpotential deposition (UPD) of Cd onto the (111) and (110) faces of copper in chloride containin...
This thesis describes results of a combined ultra-high vacuum (UHV)-electrochemistry instrument for ...
This study employed real-time in situ STM imaging to examine the adsorption of PEG molecules on Pt(1...
The structure of a chloride terminated copper monolayer electrodeposited onto Au(111) from a CuSO4/K...
The electrochemical deposition of Cu on iodine-modified Au(111) surfaces has been investigated by in...
Small Au islands of nm size are arranged in 2D piles or lines on a Au(111) surface by steering the p...
The impact of 3,3′-thiobis(1-propanesulfonic acid, sodium salt) (TBPS) on Cu/Au(111) electrodepositi...
Using cyclic voltammetry (CV), reflectance anisotropy spectroscopy (RAS), and in situ electrochemica...
Using cyclic voltammetry (CV), reflectance anisotropy spectroscopy (RAS), and in situ electrochemica...
Au(111) electrodes have been modified with self-assembled monolayers (SAM) of 3-mercapto-1-propanes...
Using cyclic voltammetry (CV), reflectance anisotropy spectroscopy (RAS), and in situ electrochemica...
Cyclic voltammetry for Cu UPD on Pd(110) in H2S04, HC104 and in Cl containing solutions has been stu...
The electrochemical deposition of a copper monolayer on Au(111) has been studied by STM in H2SO and ...
The electrochemical deposition of Cu on Au(111) surfaces covered by self-assembled thiol monolayers ...
Cu-modified Au(111) electrodes are of special interest for the design of thin films of binary Cu com...
Underpotential deposition (UPD) of Cd onto the (111) and (110) faces of copper in chloride containin...
This thesis describes results of a combined ultra-high vacuum (UHV)-electrochemistry instrument for ...
This study employed real-time in situ STM imaging to examine the adsorption of PEG molecules on Pt(1...
The structure of a chloride terminated copper monolayer electrodeposited onto Au(111) from a CuSO4/K...
The electrochemical deposition of Cu on iodine-modified Au(111) surfaces has been investigated by in...
Small Au islands of nm size are arranged in 2D piles or lines on a Au(111) surface by steering the p...
The impact of 3,3′-thiobis(1-propanesulfonic acid, sodium salt) (TBPS) on Cu/Au(111) electrodepositi...
Using cyclic voltammetry (CV), reflectance anisotropy spectroscopy (RAS), and in situ electrochemica...
Using cyclic voltammetry (CV), reflectance anisotropy spectroscopy (RAS), and in situ electrochemica...
Au(111) electrodes have been modified with self-assembled monolayers (SAM) of 3-mercapto-1-propanes...
Using cyclic voltammetry (CV), reflectance anisotropy spectroscopy (RAS), and in situ electrochemica...
Cyclic voltammetry for Cu UPD on Pd(110) in H2S04, HC104 and in Cl containing solutions has been stu...
The electrochemical deposition of a copper monolayer on Au(111) has been studied by STM in H2SO and ...
The electrochemical deposition of Cu on Au(111) surfaces covered by self-assembled thiol monolayers ...
Cu-modified Au(111) electrodes are of special interest for the design of thin films of binary Cu com...
Underpotential deposition (UPD) of Cd onto the (111) and (110) faces of copper in chloride containin...
This thesis describes results of a combined ultra-high vacuum (UHV)-electrochemistry instrument for ...
This study employed real-time in situ STM imaging to examine the adsorption of PEG molecules on Pt(1...