Implications of the spatial variability of infiltration-water chemistry for the investigation of a karst aquifer: a field study at Milandre test site, Swiss Jura

The Milandre test site is an ideal karstic aquifer for studying the spatial heterogeneity of groundwater chemistry. Numerous observation points can be sampled: the spring, the underground river and its tributaries, and boreholes at different depths. The main causes of the spatial variability of the chemical parameters are: nature and localisation of the input, the structure of the infiltration zone, chemical reactions (transit time vs. reaction kinetics) and mixing of different waters. Physico-chemical data on springs discharging from the karstic system represent the sum of this spatial heterogeneity. Therefore, it is difficult to interpret the global-chemical response with a simple mixing model of the aquifer subsystems (runoff, matrix reservoir, epikarst). Chemical constituents related to agricultural inputs show important seasonal variations (coefficient of variation approximately 15%) and parameters linked to rainfall (δ18O) and to the aquifer (Ca2+, HCO3 −) present variations of less than 5%. This result indicates the importance of water storage in the epikarstic aquifer for periods of a few month