Antimicrobial Cu-functionalized surfaces prepared by bipolar asymmetric DC-pulsed magnetron sputtering (DCP)

Cu-cotton fabrics were functionalized by bipolar asymmetric DC-pulse magnetron sputtering (DCP). The DCP of Cu-particles on cotton proceeds at a higher energy than DC-magnetron sputtering (DC). The different sputtering mode showed effects on the structure of the Cu-film on the textile. The Cu-layer thickness was observed to be a function of DCP time being the rate of atomic deposition of 2.5 × 10 15 atoms/cm2 sat 300mA. The fastest Escherichia coli inactivation was observed within 10min when Cu was sputtered on cotton Cu for 60s. This led to a film thickness of 30nm (150 Cu-layers) with 1.7×10 17 atoms/cm 2. The Cu-textiles became darker at longer sputtering times as detected by diffuse reflectance spectroscopy (DRS). By transmission electron spectroscopy (TEM), Cu-particles 35–50nm in size were found and became more compact on the cotton surface as a function of deposition time. X-ray photoelectron spectroscopy (XPS) was used to determine the surface atomic concentration of O, Cu C, and N along the states of oxidation of the Cu-ions during the redox process leading to E. coli inactivation. The oxidation of the E. coli on the Cu-cotton surface was a function of reaction time and was monitored by the oxidation index of the carbon species on the fabric according to the ratio: (C–OH)/(C–C, C C, C–H). The increase in hydrophobicity of the Cu-cotton was followed as a function of the contact angle and droplet residence time for different samples. The results obtained for the E. coli inactivation on the Cu-films are discussed suggesting a possible reaction mechanism.Fil: Osorio Vargas, Paula. Ecole Polytechnique Federale de Lausanne; SuizaFil: Sanjines, Rosendo. Ecole Polytechnique Federale de Lausanne; SuizaFil: Ruales Lonfat, Cristina. Ecole Polytechnique Federale de Lausanne; SuizaFil: Castro, Camilo. Ecole Polytechnique Federale de Lausanne; SuizaFil: Pulgarin, Cesar. Ecole Polytechnique Federale de Lausanne; SuizaFil: Rengifo Herrera, Julian Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo En Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Lavanchy, Jean-Claude. Universite de Lausanne; SuizaFil: Kiwi, John. Ecole Polytechnique Federale de Lausanne; Suiz