Models of the equation of state (EOS) type, used for describing fluid phase equilibria, typically assume that the system behavior can be described from binary contributions only. This is not enough for obtaining good predictions for the high-pressure phase equilibria of ternary highly non ideal systems. On the other hand, cubic mixing rules (CMRs) provide both, binary and ternary interaction parameters. Such ternary parameters have the potential of improving the reproduction of ternary experimental data while leaving invariant the description of the three constituent binary subsystems. In this work, we evaluate the possibilities of the CMRs approach for ternary systems by studying the phase equilibria of two of them, i.e., CO2 + n-hexadeca...
This work reports experimental phase equilibrium data for the binary systems {CO2(1) + diethyl succi...
Tricritical points (TCPs), contained in two-phase holes in three-phase surfaces, are of great import...
Texto completo: acesso restrito. p.503–509Liquid-liquid equilibrium data were correlated with three ...
Both the equation of state (EOS) and the quadratic mixing rules proposed by van der Waals towards th...
The accurate description of thermodynamic properties of asymmetric multicomponent fluid systems of i...
In this work the rich phenomenology of the ternary three-phase equilibrium is studied for a CO2(1)+H...
Phase equilibrium data at high pressures for CO2-Limonene and CO2-Citral binary systems and for CO2-...
In this work we investigated the phase equilibrium behavior of the binary asymmetric systems propane...
[[abstract]]©1994 Elsevier - A new mixing model for cubic equations of states that is theoretically ...
[[abstract]]©1992 Wiley - A new mixing rule developed for cubic equations of state equates the exces...
Modeling multiphase equilibria of mixtures comprising carbon dioxide (CO2) and organic compounds is ...
It is currently acknowledged that thermodynamic models routinely used to model the behavior of fluid...
In this work, thermodynamic models for fitting the phase equilibrium of binary systems were applied,...
The water-hydrocarbon systems are highly asymmetric. The reproduction of their experimental fluid ph...
In this work, thermodynamic models for fitting the phase equilibrium of binary systems were applied,...
This work reports experimental phase equilibrium data for the binary systems {CO2(1) + diethyl succi...
Tricritical points (TCPs), contained in two-phase holes in three-phase surfaces, are of great import...
Texto completo: acesso restrito. p.503–509Liquid-liquid equilibrium data were correlated with three ...
Both the equation of state (EOS) and the quadratic mixing rules proposed by van der Waals towards th...
The accurate description of thermodynamic properties of asymmetric multicomponent fluid systems of i...
In this work the rich phenomenology of the ternary three-phase equilibrium is studied for a CO2(1)+H...
Phase equilibrium data at high pressures for CO2-Limonene and CO2-Citral binary systems and for CO2-...
In this work we investigated the phase equilibrium behavior of the binary asymmetric systems propane...
[[abstract]]©1994 Elsevier - A new mixing model for cubic equations of states that is theoretically ...
[[abstract]]©1992 Wiley - A new mixing rule developed for cubic equations of state equates the exces...
Modeling multiphase equilibria of mixtures comprising carbon dioxide (CO2) and organic compounds is ...
It is currently acknowledged that thermodynamic models routinely used to model the behavior of fluid...
In this work, thermodynamic models for fitting the phase equilibrium of binary systems were applied,...
The water-hydrocarbon systems are highly asymmetric. The reproduction of their experimental fluid ph...
In this work, thermodynamic models for fitting the phase equilibrium of binary systems were applied,...
This work reports experimental phase equilibrium data for the binary systems {CO2(1) + diethyl succi...
Tricritical points (TCPs), contained in two-phase holes in three-phase surfaces, are of great import...
Texto completo: acesso restrito. p.503–509Liquid-liquid equilibrium data were correlated with three ...