A reaction-engineering model is presented, which describes catalyst performance as a function of the catalyst activity profile, the reaction kinetics, and the degree of catalyst deactivation. With this model, the catalyst activity profile can be optimised for Pt catalysed methyl a-D-glucopyranoside (slowly-reactive) and glucose (highly-reactive) oxidations. This is done by comparing modelling results with experimentally obtained data for catalysts of different activity distributions. Experiments in a semi-batch stirred reactor showed that for methyl a-D-glucopyranoside (MGP) oxidation at oxygen partial pressures below 40 kPa, egg shell catalytic activity distribution gives a higher rate of oxidation than a uniform distribution. It was also ...
The Pt-catalysed oxidation of the alcohol methyl a-D-glucopyranoside to 1-O-methyl a-D-glucuronic ac...
The influence of the reaction start-up procedure on the oxidation of a polyol, methyl a-D-glucopyran...
The influence of the reaction start-up procedure on the oxidation of a polyol, methyl a-D-glucopyran...
The aqueous noble metal catalysed alcohol oxidation is a reaction which can profitably be applied in...
The aqueous noble metal catalysed alcohol oxidation is a reaction which can profitably be applied in...
The aqueous noble metal catalysed alcohol oxidation is a reaction which can profitably be applied in...
The aqueous noble metal catalysed alcohol oxidation is a reaction which can profitably be applied in...
A dynamic transport model is derived to describe the platinum catalyzed aq. alc. oxidn., considering...
A dynamic transport model is derived to describe the platinum catalyzed aq. alc. oxidn., considering...
A dynamic transport model is derived to describe the platinum catalyzed aq. alc. oxidn., considering...
A dynamic transport model is derived to describe the platinum catalyzed aq. alc. oxidn., considering...
The Pt-catalysed oxidation of the alcohol methyl a-D-glucopyranoside to 1-O-methyl a-D-glucuronic ac...
The Pt-catalysed oxidation of the alcohol methyl a-D-glucopyranoside to 1-O-methyl a-D-glucuronic ac...
The Pt-catalysed oxidation of the alcohol methyl a-D-glucopyranoside to 1-O-methyl a-D-glucuronic ac...
The Pt-catalysed oxidation of the alcohol methyl a-D-glucopyranoside to 1-O-methyl a-D-glucuronic ac...
The Pt-catalysed oxidation of the alcohol methyl a-D-glucopyranoside to 1-O-methyl a-D-glucuronic ac...
The influence of the reaction start-up procedure on the oxidation of a polyol, methyl a-D-glucopyran...
The influence of the reaction start-up procedure on the oxidation of a polyol, methyl a-D-glucopyran...
The aqueous noble metal catalysed alcohol oxidation is a reaction which can profitably be applied in...
The aqueous noble metal catalysed alcohol oxidation is a reaction which can profitably be applied in...
The aqueous noble metal catalysed alcohol oxidation is a reaction which can profitably be applied in...
The aqueous noble metal catalysed alcohol oxidation is a reaction which can profitably be applied in...
A dynamic transport model is derived to describe the platinum catalyzed aq. alc. oxidn., considering...
A dynamic transport model is derived to describe the platinum catalyzed aq. alc. oxidn., considering...
A dynamic transport model is derived to describe the platinum catalyzed aq. alc. oxidn., considering...
A dynamic transport model is derived to describe the platinum catalyzed aq. alc. oxidn., considering...
The Pt-catalysed oxidation of the alcohol methyl a-D-glucopyranoside to 1-O-methyl a-D-glucuronic ac...
The Pt-catalysed oxidation of the alcohol methyl a-D-glucopyranoside to 1-O-methyl a-D-glucuronic ac...
The Pt-catalysed oxidation of the alcohol methyl a-D-glucopyranoside to 1-O-methyl a-D-glucuronic ac...
The Pt-catalysed oxidation of the alcohol methyl a-D-glucopyranoside to 1-O-methyl a-D-glucuronic ac...
The Pt-catalysed oxidation of the alcohol methyl a-D-glucopyranoside to 1-O-methyl a-D-glucuronic ac...
The influence of the reaction start-up procedure on the oxidation of a polyol, methyl a-D-glucopyran...
The influence of the reaction start-up procedure on the oxidation of a polyol, methyl a-D-glucopyran...