The successful Bose-Einstein Condensation (BEC) of alkali atoms has stimulated several groups to extend the range to metastable rare gas atoms. In 2001 this resulted in the achievement of BEC with metastable helium atoms (He^*) [1,2]. The only other rare gas atom suitable for achieving BEC is neon. The goal of our group is BEC of metastable neon (Ne^*). A condensate of metastable rare gas atoms is of special interest because their large internal energy enables real time diagnostics of the sample during condensation, giving new insight into the dynamics of the phase transition. Crucial for achieving BEC is a large (positive) scattering length. For He^* a good estimate of the order of magnitude of the scattering length was known. For neon no ...