The separated CO$_{2}$ dimer anion, (CO$_{2}$)(CO$_{2}$$^{-}$), is observed by FTIR spectroscopy in matrix isolation experiments at 1652 cm$^{-1}$ upon deposition of high energy argon ions into an argon matrix doped with 0.5\% CO$_{2}$. It has previously been reported by Andrews that upon annealing the matrix to 25K, the separated species converts to an oxalate-like C$_{2}$O$_{4}$$^{-}$ species which appears at 1856 cm$^{-1}$.$^{a}$ We have observed that subsequently holding the matrix at 10K caused the C$_{2}$O$_{4}$$^{-}$ species to fully convert back to (CO$_{2}$)(CO$_{2}$$^{-}$). Upon further investigation, we determined that the two species reversibly interconvert between 19K and 23K, suggesting the species are in thermodynamic equilib...
The effects of CO2 molecules upon an argon thermal plasma at atmospheric pressure are studied by op...
We present a computational survey of the reduction of CO2 to CO by alkali metal and alkaline earth m...
Millimeter observations of pre- and protostellar cores show that the abundances of the gas-phase tra...
The separated CO$_{2}$ dimer anion, (CO$_{2}$)(CO$_{2}$$^{-}$), is observed by FTIR spectroscopy in ...
The interactions of FeBr2, CoBr2, NiBr2 and ZnBr2 with Ne, Ar, Kr, Xe, CH4 and N2 matrices have been...
Neutral and anionic clusters containing carbon monoxide and carbon dioxide molecules were observed i...
Using matrix isolation FTIR, we have observed the formation of anionic copper carbonyl complexes [Cu...
Vibrational energies for low-lying levels of CO2 trapped in rare gas matrices are determined for fou...
Bands corresponding to structural isomers of matrix-isolated O$_{4}$$^{+}$ are observed upon deposit...
Author Institution: Dartmouth College, Hanover, NH 03755; University of Colorado, Boulder, CO 80309A...
Glycolic acid (GA) dimers were studied in low temperature argon matrices by means of FTIR spectrosco...
The concentrations of water dimer are compared in Ne and p-H-2 matrices at low temperatures, using i...
Infrared absorption spectra of HC1 and HBr, suspended in solid argon, krypton and nitrogen, were rec...
Millimeter observations of pre- and protostellar cores show that the abundances of the gas-phase tra...
$^{a}$ P.A. Vanden Bout, J.M. Steed, L.S. Bernstein, and W. Klemperer, Astrophys. J. 234, 503 (1979)...
The effects of CO2 molecules upon an argon thermal plasma at atmospheric pressure are studied by op...
We present a computational survey of the reduction of CO2 to CO by alkali metal and alkaline earth m...
Millimeter observations of pre- and protostellar cores show that the abundances of the gas-phase tra...
The separated CO$_{2}$ dimer anion, (CO$_{2}$)(CO$_{2}$$^{-}$), is observed by FTIR spectroscopy in ...
The interactions of FeBr2, CoBr2, NiBr2 and ZnBr2 with Ne, Ar, Kr, Xe, CH4 and N2 matrices have been...
Neutral and anionic clusters containing carbon monoxide and carbon dioxide molecules were observed i...
Using matrix isolation FTIR, we have observed the formation of anionic copper carbonyl complexes [Cu...
Vibrational energies for low-lying levels of CO2 trapped in rare gas matrices are determined for fou...
Bands corresponding to structural isomers of matrix-isolated O$_{4}$$^{+}$ are observed upon deposit...
Author Institution: Dartmouth College, Hanover, NH 03755; University of Colorado, Boulder, CO 80309A...
Glycolic acid (GA) dimers were studied in low temperature argon matrices by means of FTIR spectrosco...
The concentrations of water dimer are compared in Ne and p-H-2 matrices at low temperatures, using i...
Infrared absorption spectra of HC1 and HBr, suspended in solid argon, krypton and nitrogen, were rec...
Millimeter observations of pre- and protostellar cores show that the abundances of the gas-phase tra...
$^{a}$ P.A. Vanden Bout, J.M. Steed, L.S. Bernstein, and W. Klemperer, Astrophys. J. 234, 503 (1979)...
The effects of CO2 molecules upon an argon thermal plasma at atmospheric pressure are studied by op...
We present a computational survey of the reduction of CO2 to CO by alkali metal and alkaline earth m...
Millimeter observations of pre- and protostellar cores show that the abundances of the gas-phase tra...