The catalyzed reduction of CO$_{2}$ is an important step in the conversion of this small molecule into liquid fuels. Nickel 1,4,8,11-tetraazacyclotetradecane, Ni(cyclam), is a well-known catalyst for the reduction of CO$_{2}$ in solution. Cryogenic ion vibrational predissociation (CIVP) spectroscopy of CO$_{2}$-messenger tagged ions cooled in a temperature controlled ion trap was used to study the starting Ni$^{2+}$(cyclam) reactant, and possible reaction intermediates and products in the gas phase. Additionally, parental CO$_{2}$ reduction was observed on the Ni(I) species [Ni(bipyridine-(NMe)$_{2}$)]$_{2}$(diphenyldiacetylene)
Author Institution: Department of Chemistry, Yale University, New Haven, Ct 06520Two aspects of cata...
The catalytic conversion of carbon dioxide to synthetic fuels and other valuable chemicals is an iss...
The main part of this work, deals with the reactivity of a sterically challenging nickel(II) azamacr...
The catalyzed reduction of CO$_{2}$ is an important step in the conversion of this small molecule in...
Catalytic reduction of CO$_{2}$ to produce chemical fuels is a viable strategy for meeting the growi...
The homogeneous electrochemical reduction of CO₂ by the molecular catalyst [Ni(cyclam)]2+ was studie...
Catalytic reduction of CO$_{2}$ to produce chemical fuels is a viable strategy for meeting the growi...
The homogeneous electrochemical reduction of CO<sub>2</sub> by the molecular catalyst [Ni(cyclam)]<...
We report the synthesis of Ni(TAPPy)2 (TAPPy = 1,3,5-triazapentadienyl-2,4-bis(2-pyridyl)) and its r...
Author Institution: Department of Chemistry, Yale University, New Haven, Ct 06520Transition metal-ba...
Rosenthal, JoelElectrochemical CO2 reduction was first tested on N-methylated nickel cyclen derivati...
In this work, molecular complexes of transition metals have been synthesised and studied for their C...
The reaction of a zerovalent nickel complex {Na}{(PNP)Ni(CO)} (1) with CO2(g) results in the formati...
The electrochemical reduction of carbon dioxide is strongly catalysed when it is carried out by cath...
The efficiency of the reduction of carbon dioxide catalysed by 1,4,8,11- tetraazacyclotetradecane ni...
Author Institution: Department of Chemistry, Yale University, New Haven, Ct 06520Two aspects of cata...
The catalytic conversion of carbon dioxide to synthetic fuels and other valuable chemicals is an iss...
The main part of this work, deals with the reactivity of a sterically challenging nickel(II) azamacr...
The catalyzed reduction of CO$_{2}$ is an important step in the conversion of this small molecule in...
Catalytic reduction of CO$_{2}$ to produce chemical fuels is a viable strategy for meeting the growi...
The homogeneous electrochemical reduction of CO₂ by the molecular catalyst [Ni(cyclam)]2+ was studie...
Catalytic reduction of CO$_{2}$ to produce chemical fuels is a viable strategy for meeting the growi...
The homogeneous electrochemical reduction of CO<sub>2</sub> by the molecular catalyst [Ni(cyclam)]<...
We report the synthesis of Ni(TAPPy)2 (TAPPy = 1,3,5-triazapentadienyl-2,4-bis(2-pyridyl)) and its r...
Author Institution: Department of Chemistry, Yale University, New Haven, Ct 06520Transition metal-ba...
Rosenthal, JoelElectrochemical CO2 reduction was first tested on N-methylated nickel cyclen derivati...
In this work, molecular complexes of transition metals have been synthesised and studied for their C...
The reaction of a zerovalent nickel complex {Na}{(PNP)Ni(CO)} (1) with CO2(g) results in the formati...
The electrochemical reduction of carbon dioxide is strongly catalysed when it is carried out by cath...
The efficiency of the reduction of carbon dioxide catalysed by 1,4,8,11- tetraazacyclotetradecane ni...
Author Institution: Department of Chemistry, Yale University, New Haven, Ct 06520Two aspects of cata...
The catalytic conversion of carbon dioxide to synthetic fuels and other valuable chemicals is an iss...
The main part of this work, deals with the reactivity of a sterically challenging nickel(II) azamacr...