Nanoscale study on water damage for different warm mix asphalt binders

In order to analyze the water damage to different warm mix asphalt binders from the micro scale, five kinds of asphalt binders, 70#A base asphalt, sasobit warm mix asphalt, energy champion 120 °C (EC120) warm mix asphalt, aspha-min warm mix asphalt, sulfur-extended asphalt modifier (SEAM) warm mix asphalt, under different conditions (dry/wet, original/aging) are prepared for laboratory tests. The atomic force microscope (AFM) is used to observe the surface properties and measure the adhesion force between the asphalt and the mineral aggregate. The obtained results show that under the dry condition aspha-min warm mix asphalt and SEAM warm mix asphalt show stronger adhesive ability with the mineral aggregate compared with other asphalt binders, but also have relatively large dispersion and fluctuation in the tested results; under the wet condition, aspha-min warm mix asphalt and SEAM warm mix asphalt show stronger water damage resistance ability. The EC120 warm mix asphalt and aspha-min warm mix asphalt are less sensitive to moist, and their corresponding adhesion force is less susceptible to the change of external moisture conditions, leading to a better ability to resist water erosion. The aging process significantly lowers the moisture erosion resistance ability, which further impairs the water damage resistance ability. The base asphalt is more sensitive to moisture and more vulnerable to water damage, no matter whether it is under original or aging conditions. The aging aspha-min warm mix asphalt has the least loss of adhesion force, the smallest dispersion of the tested adhesion force, the strongest water damage resistance ability, no matter it is dry or wet. Keywords: Road engineering, Warm mix asphalt, Moisture damage, Atomic force microscope, Microcosmi