Dynamic Impact of RuCl3 Catalyst on the Oxidation of Cyclamate with Acidified Bromamine-T: Elucidation of Mechanistic Pathways and Kinetic Modeling

Abstract: Oxidation-Kinetics of cyclamate by bromamine-T (BAT) in HClO4 medium catalyzed by RuCl3 exhibits a first-order dependence on BAT0, fractional-order on both Cyclamate0 and RuCl3, and inverse fractional-order on HClO4. RuCl3 catalyst accelerated the reaction by a splendid 48 times. Plausible mechanism and related rate law have been deduced. Graphical Abstract: The Stoichiometry of the reaction is:Figure not available: see fulltext.. © 2017, Springer Science+Business Media New York