We study the problem of a single ideal polymer chain tethered to a surface at the midpoint of a repulsive potential stripe. If the potential is very weak, the chain remains unperturbed. However, as the potential is increased, the chain conformation undergoes a sudden change. The chain forms a tether to the edge of the stripe and moves most of the monomers off to the region of lower potential. This is a simple example of an escape transition previously discussed for compression of polymer chains. We show how these two systems are analogous and clear up some controversy regarding the exact form of the force versus height curve for the compressive system
We consider a stiff polymer chain in poor solvent and apply a force at one end of the chain. We find...
We review some recent results obtained by our group, on the generai subject of polymers confined wit...
The flow-induced coil-stretch transition of high molecular weight polymers has generally been held t...
ABSTRACT: We study the problem of a single ideal polymer chain tethered to a surface at the midpoint...
The problem of a polymer confined within a slit is a classic problem that is generally well understo...
Upon compression between two pistons an end-tethered polymer chain undergoes an abrupt transition fr...
The escape transition of a flexible polymer chain of chain length N, endgrafted at a hard wall and c...
An end-tethered polymer chain compressed between two pistons undergoes an abrupt transition from a c...
We study the problem of a single surface-tethered polymer chain or “mushroom” compressed by a curved...
The rate of escape of polymers from a two-dimensionally confining potential well has been evaluated ...
We analyze exact analytical partition functions for Gaussian chains near surfaces and interfaces. Th...
The exact partition of the gaussian chain squeezed between two cylinders for a phase transition in a...
We consider the forced escape of a polymer out of a potential well. The process has two steps – cros...
We consider the breaking of a polymer molecule which is fixed at one end and is acted upon by a forc...
The analysis of the exact partition function of an end-fixed Gaussian chain compressed between two p...
We consider a stiff polymer chain in poor solvent and apply a force at one end of the chain. We find...
We review some recent results obtained by our group, on the generai subject of polymers confined wit...
The flow-induced coil-stretch transition of high molecular weight polymers has generally been held t...
ABSTRACT: We study the problem of a single ideal polymer chain tethered to a surface at the midpoint...
The problem of a polymer confined within a slit is a classic problem that is generally well understo...
Upon compression between two pistons an end-tethered polymer chain undergoes an abrupt transition fr...
The escape transition of a flexible polymer chain of chain length N, endgrafted at a hard wall and c...
An end-tethered polymer chain compressed between two pistons undergoes an abrupt transition from a c...
We study the problem of a single surface-tethered polymer chain or “mushroom” compressed by a curved...
The rate of escape of polymers from a two-dimensionally confining potential well has been evaluated ...
We analyze exact analytical partition functions for Gaussian chains near surfaces and interfaces. Th...
The exact partition of the gaussian chain squeezed between two cylinders for a phase transition in a...
We consider the forced escape of a polymer out of a potential well. The process has two steps – cros...
We consider the breaking of a polymer molecule which is fixed at one end and is acted upon by a forc...
The analysis of the exact partition function of an end-fixed Gaussian chain compressed between two p...
We consider a stiff polymer chain in poor solvent and apply a force at one end of the chain. We find...
We review some recent results obtained by our group, on the generai subject of polymers confined wit...
The flow-induced coil-stretch transition of high molecular weight polymers has generally been held t...