Add to ORKGAb initio calculations at the G2 level have been employed to investigate the hitherto unobserved π-ligand exchange reactions of thiirenium and thiiranium ions. Two pathways for exchange and one pathway for insertion are presented. The lower energy excha
The introduction of thianthrene as a linchpin has proven to be a versatile strategy for the C–H func...
Abstraction of a Cl− ion from the P‐chlorophospholes, R4C4PCl (R=Me, Et), produced the P-P bonded ca...
A detailed experimental and DFT study (PBE level) of the reaction of [Pd(η3-C3H5)(tmiy)(PR3)]BF4 (tm...
Generally, the bimolecular nucleophilic substitution at the saturated carbon (S(N)2) and the mechani...
Thiourea and its derivatives often act as strong electron-donating ligands in palladium-catalyzed re...
Despite numerous computational and experimental studies on the π‐ligand exchange reactions of chalco...
A ligand exchange of one of the acetonitrile ligands of the (acetonitrile)4Ru(II)–phenyloxazoline c...
Generally, the bimolecular nucleophilic substitution at the saturated carbon (SN2) and the mechanist...
Abstraction of a Cl(-) ion from the P-chlorophospholes, R4C4PCl (R=Me, Et), produced the P--P bonded...
Abstraction of a Cl- ion from the P-chlorophospholes, R4C4PCl (R=Me, Et), produced the PP bonded cat...
International audienceMany reactions of transition metal compounds involve a change in spin. These r...
International audienceThe exchange of the phosphine ligand on the half-sandwich 15-electron, spin qu...
This chapter discusses the mechanisms of solvent exchange and ligand substitution on solvated metal ...
International audienceIn coordination chemistry, many reactions involve several electronic states, i...
The ion molecule reactions between C5H5M+ (M =Fe, Ni) with some substituted thiophenes have been stu...
The introduction of thianthrene as a linchpin has proven to be a versatile strategy for the C–H func...
Abstraction of a Cl− ion from the P‐chlorophospholes, R4C4PCl (R=Me, Et), produced the P-P bonded ca...
A detailed experimental and DFT study (PBE level) of the reaction of [Pd(η3-C3H5)(tmiy)(PR3)]BF4 (tm...
Generally, the bimolecular nucleophilic substitution at the saturated carbon (S(N)2) and the mechani...
Thiourea and its derivatives often act as strong electron-donating ligands in palladium-catalyzed re...
Despite numerous computational and experimental studies on the π‐ligand exchange reactions of chalco...
A ligand exchange of one of the acetonitrile ligands of the (acetonitrile)4Ru(II)–phenyloxazoline c...
Generally, the bimolecular nucleophilic substitution at the saturated carbon (SN2) and the mechanist...
Abstraction of a Cl(-) ion from the P-chlorophospholes, R4C4PCl (R=Me, Et), produced the P--P bonded...
Abstraction of a Cl- ion from the P-chlorophospholes, R4C4PCl (R=Me, Et), produced the PP bonded cat...
International audienceMany reactions of transition metal compounds involve a change in spin. These r...
International audienceThe exchange of the phosphine ligand on the half-sandwich 15-electron, spin qu...
This chapter discusses the mechanisms of solvent exchange and ligand substitution on solvated metal ...
International audienceIn coordination chemistry, many reactions involve several electronic states, i...
The ion molecule reactions between C5H5M+ (M =Fe, Ni) with some substituted thiophenes have been stu...
The introduction of thianthrene as a linchpin has proven to be a versatile strategy for the C–H func...
Abstraction of a Cl− ion from the P‐chlorophospholes, R4C4PCl (R=Me, Et), produced the P-P bonded ca...
A detailed experimental and DFT study (PBE level) of the reaction of [Pd(η3-C3H5)(tmiy)(PR3)]BF4 (tm...