The thermodynamics and structure of the surface adsorbed phase in binary C15-C16 and C15-C17 n-alkane mixtures confined in graphite pores have been studied by differential scanning calorimetry and small-angle X-ray scattering. The previously observed selective adsorption of the longer alkane for chain length differences greater than five carbon atoms is verified but reduced for chain length differences less than or equal to two. With a difference in chain length of one carbon atom, Vegard's law is followed for the melting points of the adsorbed mixture and the (0 2) d-spacing is a continuous function of the mole fraction x. With a two-carbon atom difference, samples aged for 1 week have a lamellar structure for which the entities A1-xBx try...
A previous study of the desorption of straight-chain alkanes [H(CH2)NH, N) 5-60] from the surface of...
The mixing behavior of binary combinations of linear alcohols adsorbed from their liquids is studied...
Adsorption of shale related n-alkane fluids in graphite nano-channels is studied. Pure component can...
In this work, we present the behavior of solid monolayers of binary mixtures of alkanes and alcohols...
A novel combination of sensitive calorimetry, neutron diffraction and NMR have been used to investig...
The competitive adsorption of n-decane and n-heptan-1-ol adsorbed from the binary liquid mixture ont...
We report a thermodynamic investigation of the adsorption of saturated and unsaturated (cis- and tra...
The behaviour of binary mixtures of octane and nonane adsorbed on graphite has been investigated wit...
The structure of graphite-adsorbed n-alkanes for 10 ≤ n ≤ 20 has been investigated by SAXS. Below th...
The combination of sensitive calorimetry, incoherent elastic neutron scattering and neutron di†racti...
URL:http://link.aps.org/doi/10.1103/PhysRevLett.75.3154 DOI:10.1103/PhysRevLett.75.3154Neutron diff...
The mixing behavior of binary combinations of perfluoroalkanes in the bulk and in solid monolayers a...
The phase transitions of two n-alkanes of different parity, C 16H34 and C17H36, confined in the meso...
The dynamics of oligomer desorption from surfaces have been studied by measuring the desorption kine...
Molecular simulations using the Configurational-bias Monte Carlo technique were performed to calcula...
A previous study of the desorption of straight-chain alkanes [H(CH2)NH, N) 5-60] from the surface of...
The mixing behavior of binary combinations of linear alcohols adsorbed from their liquids is studied...
Adsorption of shale related n-alkane fluids in graphite nano-channels is studied. Pure component can...
In this work, we present the behavior of solid monolayers of binary mixtures of alkanes and alcohols...
A novel combination of sensitive calorimetry, neutron diffraction and NMR have been used to investig...
The competitive adsorption of n-decane and n-heptan-1-ol adsorbed from the binary liquid mixture ont...
We report a thermodynamic investigation of the adsorption of saturated and unsaturated (cis- and tra...
The behaviour of binary mixtures of octane and nonane adsorbed on graphite has been investigated wit...
The structure of graphite-adsorbed n-alkanes for 10 ≤ n ≤ 20 has been investigated by SAXS. Below th...
The combination of sensitive calorimetry, incoherent elastic neutron scattering and neutron di†racti...
URL:http://link.aps.org/doi/10.1103/PhysRevLett.75.3154 DOI:10.1103/PhysRevLett.75.3154Neutron diff...
The mixing behavior of binary combinations of perfluoroalkanes in the bulk and in solid monolayers a...
The phase transitions of two n-alkanes of different parity, C 16H34 and C17H36, confined in the meso...
The dynamics of oligomer desorption from surfaces have been studied by measuring the desorption kine...
Molecular simulations using the Configurational-bias Monte Carlo technique were performed to calcula...
A previous study of the desorption of straight-chain alkanes [H(CH2)NH, N) 5-60] from the surface of...
The mixing behavior of binary combinations of linear alcohols adsorbed from their liquids is studied...
Adsorption of shale related n-alkane fluids in graphite nano-channels is studied. Pure component can...