Dinitrogen metal complexes with a strongly activated N-N bond: a computational investigation of [(Cy 2 N) 3 Nb-(μ-NN)-Nb(NCy 2 ) 3 ] and related [Nb-(μ-NN)-Nb] systems

Cavigliasso, German
Stranger, Robert
Yates, Brian F

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Publication date

February 2016

DOI

10.1039/C2DT31845H

Publisher

Royal Society of Chemistry (RSC)

Journal

Dalton Transactions

Abstract

The structural and bonding properties of the dinitrogen-bridged diniobium [(Cy2N)3Nb(μ-NN)Nb(NCy2)3] complex experimentally characterized by Berno and Gambarotta, which exhibits a strongly activated N-N bond of 134 pm, have been explored using density f

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Dinitrogen metal complexes with a strongly activated N-N bond: a computational investigation of [(Cy 2 N) 3 Nb-(μ-NN)-Nb(NCy 2 ) 3 ] and related [Nb-(μ-NN)-Nb] systems

Abstract

Extracted data

Dinitrogen metal complexes with a strongly activated N-N bond: a computational investigation of [(Cy 2 N) 3 Nb-(μ-NN)-Nb(NCy 2 ) 3 ] and related [Nb-(μ-NN)-Nb] systems

Abstract

Extracted data

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